Evaluation of the reliability of Si3N4-Al2O3 -CTR2O3 ceramics through Weibull analysis

Autor(es)

Claudinei dos Santos ^[1] ; Kurt Strecker ^[2] ; Francisco Piorino Neto ^[3] ; Olivério Moreira de Macedo Silva ^[4] ; Sandro Aparecido Baldacim ^[5] ; Cosme Roberto Moreira da Silva ^[6]

Afiliação do(s) autor(es)

^[1] FAENQUIL Polo Urbo Industrial. Departamento de Engenharia de Materiais - Brasil

^[2] FAENQUIL Polo Urbo Industrial. Departamento de Engenharia de Materiais - Brasil

^[3] IAE. CTA. Divisão de Materiais AMR - Brasil

^[4] IAE. CTA. Divisão de Materiais AMR - Brasil

^[5] IAE. CTA. Divisão de Materiais AMR - Brasil

^[6] IAE. CTA. Divisão de Materiais AMR - Brasil

• Tipo de documento: Artigo Científico
• Fonte: MATERIALS RESEARCH-IBERO-AMERICAN JOURNAL OF MATERIALS; v. 6, n. 4, p. 463-467, 2003-12-00.

Resumo

The objective of this work has been to compare the reliability of two Si3N4 ceramics, with Y2O3/Al2O3 or CTR2O3/Al2O3 mixtures as additives, in regard to their 4-point bending strength and to confirm the potential of the rare earth oxide mixture, CTR2O3, produced at FAENQUIL, as an alternative, low cost sinter additive for pure Y2O3 in the sintering of Si3N4 ceramics. The oxide mixture CTR2O3 is a solid solution formed mainly by Y2O3, Er2O3, Yb2O3 and Dy2O3 with other minor constituents and is obtained at a cost of only 20% of pure Y2O3. Samples were sintered by a gas pressure sintering process at 1900 °C under a nitrogen pressure of 1.5 MPa and an isothermal holding time of 2 h. The obtained materials were characterized by their relative density, phase composition and bending strength. The Weibull analysis was used to describe the reliability of these materials. Both materials produced presented relative densities higher than 99.5%t.d., b-Si3N4 and Y3Al5O12 (YAG) as cristalline phases and bending strengths higher than 650 MPa, thus demonstrating similar behaviors regarding their physical, chemical and mechanical characteristics. The statistical analysis of their strength also showed similar results for both materials, with Weibull moduli m of about 15 and characteristic stress values s o of about 700 MPa. These results confirmed the possibility of using the rare earth oxide mixture, CTR2O3, as sinter additive for high performance Si3N4 ceramics, without prejudice of the mechanical properties when compared to Si3N4 ceramics sintered with pure Y2O3. (AU)

• Processo FAPESP: 01/08682-6 - Estudo dos mecanismos de fluência do Si3N4 prensado a quente, aditivado com CTR2O3/AIN e CTR2O3/AI2O3
• Beneficiário: Claudinei dos Santos
• Modalidade de apoio: Bolsas no Brasil - Doutorado