Analysis of the polymeric fractions of scrap from mobile phones using laser-induced breakdown spectroscopy: Chemometric applications for better data interpretation

Autor(es)

Aquino, Francisco W. B. ^[1] ; Pereira-Filho, Edenir R. ^[1]

Afiliação do(s) autor(es)

^[1] Univ Fed Sao Carlos UFSCar, Dept Quim, Grp Anal Instrumental Aplicada, BR-13565905 Sao Carlos, SP - Brazil

• Tipo de documento: Artigo Científico
• Fonte: Talanta; v. 134, p. 65-73, MAR 1 2015.
• Citações Web of Science: 27

Resumo

Because of their short life span and high production and consumption rates, mobile phones are one of the contributors to WEEE (waste electrical and electronic equipment) growth in many countries. If incorrectly managed, the hazardous materials used in the assembly of these devices can pollute the environment and pose dangers for workers involved in the recycling of these materials. In this study, 144 polymer fragments originating from 50 broken or obsolete mobile phones were analyzed via laserinduced breakdown spectroscopy (LIBS) without previous treatment. The coated polymers were mainly characterized by the presence of Ag, whereas the uncoated polymers were related to the presence of Al, K, Na, Si and Ti. Classification models were proposed using black and white polymers separately in order to identify the manufacturer and origin using KNN (K-nearest neighbor), SIMCA (Soft Independent Modeling of Class Analogy) and PLS-DA (Partial Least Squares for Discriminant Analysis). For the black polymers the percentage of correct predictions was, in average, 58% taking into consideration the models for manufacturer and origin identification. In the case of white polymers, the percentage of correct predictions ranged from 72.8% (PLS-DA) to 100% (KNN). (C) 2014 Elsevier B.V. All rights reserved. (AU)

• Processo FAPESP: 12/50827-6 - Readequação física dos laboratórios do grupo de análise instrumental aplicada (Gaia) para a proposição de métodos analíticos de análise de lixo eletrônico e de cosméticos
• Beneficiário: Edenir Rodrigues Pereira Filho
• Modalidade de apoio: Auxílio à Pesquisa - Regular
• Processo FAPESP: 13/04688-7 - Desenvolvimento de métodos espectroanalíticos para a determinação direta de elementos tóxicos em materiais poliméricos de lixo eletrônico por emissão em plasma induzido por laser (LIBS)
• Beneficiário: Francisco Wendel Batista de Aquino
• Modalidade de apoio: Bolsas no Brasil - Pós-Doutorado
• Processo FAPESP: 12/01769-3 - Desenvolvimento de métodos espectroanalíticos para a análise direta de amostras de lixo eletrônico e de cosméticos
• Beneficiário: Edenir Rodrigues Pereira Filho
• Modalidade de apoio: Auxílio à Pesquisa - Regular