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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Analysis of the polymeric fractions of scrap from mobile phones using laser-induced breakdown spectroscopy: Chemometric applications for better data interpretation

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Author(s):
Aquino, Francisco W. B. [1] ; Pereira-Filho, Edenir R. [1]
Total Authors: 2
Affiliation:
[1] Univ Fed Sao Carlos UFSCar, Dept Quim, Grp Anal Instrumental Aplicada, BR-13565905 Sao Carlos, SP - Brazil
Total Affiliations: 1
Document type: Journal article
Source: Talanta; v. 134, p. 65-73, MAR 1 2015.
Web of Science Citations: 27
Abstract

Because of their short life span and high production and consumption rates, mobile phones are one of the contributors to WEEE (waste electrical and electronic equipment) growth in many countries. If incorrectly managed, the hazardous materials used in the assembly of these devices can pollute the environment and pose dangers for workers involved in the recycling of these materials. In this study, 144 polymer fragments originating from 50 broken or obsolete mobile phones were analyzed via laserinduced breakdown spectroscopy (LIBS) without previous treatment. The coated polymers were mainly characterized by the presence of Ag, whereas the uncoated polymers were related to the presence of Al, K, Na, Si and Ti. Classification models were proposed using black and white polymers separately in order to identify the manufacturer and origin using KNN (K-nearest neighbor), SIMCA (Soft Independent Modeling of Class Analogy) and PLS-DA (Partial Least Squares for Discriminant Analysis). For the black polymers the percentage of correct predictions was, in average, 58% taking into consideration the models for manufacturer and origin identification. In the case of white polymers, the percentage of correct predictions ranged from 72.8% (PLS-DA) to 100% (KNN). (C) 2014 Elsevier B.V. All rights reserved. (AU)

FAPESP's process: 13/04688-7 - Development of spectroanalytical methods for direct determination of toxic elements in polymeric materials of electronic waste by laser-induced breakdown spectroscopy
Grantee:Francisco Wendel Batista de Aquino
Support Opportunities: Scholarships in Brazil - Post-Doctoral
FAPESP's process: 12/01769-3 - Development of spectroanalytical methods for direct analysis of waste electrical and electronic equipments and cosmetics
Grantee:Edenir Rodrigues Pereira Filho
Support Opportunities: Regular Research Grants