Bio-ethanol steam reforming for hydrogen production over Co3O4/CeO2 catalysts synthesized by one-step polymerization method

Autor(es)

Carvalho, Flavio L. S. ^[1] ; Asencios, Yvan J. O. ^[2] ; Bellido, Jorge D. A. ^[3] ; Assaf, Elisabete M. ^[1]

Afiliação do(s) autor(es)

^[1] Univ Sao Paulo, Inst Quim Sao Carlos, BR-13560970 Sao Carlos, SP - Brazil

^[2] Univ Fed Sao Paulo, Dept Ciencias Mar, BR-11030400 Santos, SP - Brazil

^[3] Univ Fed Sao Joao Del Rei, Dept Engn Quim, Ouro Branco, MG - Brazil

• Tipo de documento: Artigo Científico
• Fonte: Fuel Processing Technology; v. 142, p. 182-191, FEB 2016.
• Citações Web of Science: 31

Resumo

Bio-ethanol is a renewable energy carrier and its use in the reforming of bio-ethanol is promising for hydrogen production. In this work, a set of materials containing mixtures of Co3O4/CeO2 (5, 10 and 20% Co wt.%) were synthesized by one-step polymerization method (OSP method), and were tested in ethanol steam reforming (SRE). For comparison purposes, the best catalyst of this set was compared with a similar one synthesized by the impregnation method. The XRD, SEM and TPR analyses of the CoCe catalysts prepared by the OSP method showed that the increase of the cobalt content increases Co-O-Ce interaction, this interaction had positive effects on the catalysis of SRE. The OSP method provides a more homogeneous material leading to finely dispersed metallic cobalt which favored the catalysis of the SRE at 500 degrees C; the best catalyst was the Co3O4/CeO2 mixture with cobalt content of 20 wt.% (20CoCe catalyst). This catalyst reported high metallic dispersion, high-surface-area, high selectivity to H-2, good catalytic stability and low carbon deposition rate. This catalyst is promising for the steam reforming of bio-ethanol. The catalyst prepared by the impregnation method was not good for the catalysis of SRE at 500 degrees C. (C) 2015 Elsevier B.V. All rights reserved. (AU)

• Processo FAPESP: 09/15984-0 - Produção de bioenergia no tratamento de águas residuárias e adequação ambiental dos efluentes e resíduos gerados
• Beneficiário: Marcelo Zaiat
• Modalidade de apoio: Auxílio à Pesquisa - Temático