The glassy state of matter: Its definition and ultimate fate

Autor(es)

Zanotto, Edgar D. ; Mauro, John C.

• Tipo de documento: Artigo Científico
• Fonte: Journal of Non-Crystalline Solids; v. 471, p. 490-495, SEP 1 2017.
• Citações Web of Science: 44

Resumo

The objective of this communication is to clarify the meanings of solid and liquid, to dwell on the ultimate fate of glass in the limit of infinitely long time, and to propose a modern, improved definition of glass. We review the four characteristic states of matter related to vitrification: the stable equilibrium liquid (L), the metastable supercooled liquid (SCL), the unstable nonequilibrium glass (G), and the stable crystal (C). We also discuss some relevant terms and phenomena, including glass transition, crystallization, non-crystalline, amorphous, solid, and frozen. We review several previously published definitions of glass and finally propose an improved definition in two alternative forms. The first improved definition is: ``Glass is a nonequilibrium, non-crystalline state of matter that appears solid on a short time scale but continuously relaxes towards the liquid state.{''} This is an intuitive description for the general public and young students. An alternative, more detailed definition to be understood and used by advanced students, researchers, and professors is: ``Glass is a nonequilibrium, noncrystalline condensed state of matter that exhibits a glass transition. The structure of glasses is similar to that of their parent supercooled liquids (SCL), and they spontaneously relax toward the SCL state. Their ultimate fate, in the limit of infinite time, is to crystallize.{''} This definition is for experts who understand the meaning of glass transition. (AU)

• Processo FAPESP: 13/07793-6 - CEPIV - Centro de Ensino, Pesquisa e Inovação em Vidros
• Beneficiário: Edgar Dutra Zanotto
• Modalidade de apoio: Auxílio à Pesquisa - Centros de Pesquisa, Inovação e Difusão - CEPIDs