Solvation by aqueous solutions of imidazole-based ionic liquids: 2-A comparison between alkyl and alkoxy side-chains

Autor(es)

de Jesus, Jessica C. ^[1] ; Pires, Paulo A. R. ^[1] ; Scharf, Magdalena ^[2] ; El Seoud, Omar A. ^[1]

Afiliação do(s) autor(es)

^[1] Univ Sao Paulo, Inst Chem, 748 Prof Lineu Prestes Av, BR-05508000 Sao Paulo, SP - Brazil

^[2] Philipps Univ Marburg, Dept Pharmaceut Chem, Marbacher Weg 6, D-35032 Marburg - Germany

• Tipo de documento: Artigo Científico
• Fonte: Fluid Phase Equilibria; v. 451, p. 48-56, NOV 15 2017.
• Citações Web of Science: 4

Resumo

Binary mixtures of ionic liquids (ILs) and molecular solvents are employed for practical reasons, e.g., reduction of solution viscosity and overcoming solubility/miscibility problems. We obtain information on solvation in these media from solvent properties, e.g., empirical polarity ET(probe) calculated from the spectra of solvatochromic probes. To evaluate the effect on solvation of the IL cation side-chain we studied the solvatochromic response of the polarity probe WB (2,6-dichloro-4-(2,4,6-triphenylpyridinium-1-ye phenolate) dissolved in the following aqueous ILs: 1-R-3-methylimidazoliumAcO, where R = 1-heptyl, C(7)MeImAcO; and 3,6-dioxa-(1-heptY1), C(5)O(2)MeImAcO; AcO = acetate; in the temperature range 15-60 degrees C. The relative acidity of the imidazolium ring hydrogens bears on solvation. Consequently, we extended our study to aqueous solutions of 1-R'-1,2-dimethylimidazoliumAcO, R' = 1-butyl (C(4)Me(2)ImAcO) and methoxyethyl (C(3)OMe(2)ImAcO). Our results showed that the expected effect of the side-chain ether oxygen on El(WB) is impaired by formation of intramolecular hydrogen bonding, e.g., with hydrogens of the imidazolium ring. We corroborated this conclusion by H-1 NMR data, and theoretical calculations (molecular dynamics simulations; quantum chemistry calculations). Introducing second ether oxygen (C(5)O(2)MeImAcO) and replacing C2-H by C2-CH3 in the imidazolium ring (C(3)OMe(2)ImAcO) increased the difference in polarity between ILs with alkoxy and alkyl side-chains. For C(7)MeImAcO and C(5)O(2)MelmAcO the dependence of ET(WB) on the water mole fraction was treated according to a model that includes solvation by the complex solvent (IL ... water); the latter is the most efficient solvent species present because it forms more hydrogen-bonds with the phenolate oxygen of WB. (C) 2017 Elsevier B.V. All rights reserved. (AU)

• Processo FAPESP: 14/22136-4 - Uso de solventes verdes e suas misturas na otimização de processos químicos
• Beneficiário: Omar Abou El Seoud
• Modalidade de apoio: Auxílio à Pesquisa - Temático
• Processo FAPESP: 16/13932-7 - Solvatação em misturas binárias de líquidos iônicos-solventes moleculares: efeitos da composição das misturas, da temperatura e aplicação na dissolução de celulose
• Beneficiário: Jessica Carol de Jesus
• Modalidade de apoio: Bolsas no Brasil - Iniciação Científica