Graphene oxide nanomaterials for the removal of non-ionic surfactant from water

Autor(es)

Prediger, Patricia ^[1] ; Cheminski, Thais ^[1] ; Neves, Tauany de Figueiredo ^[1] ; Nunes, William Bardelin ^[1] ; Sabino, Livia ^[1] ; Franco Picone, Carolina Siqueira ^[2] ; Oliveira, Rafael L. ^[3] ; Duarte Correia, Carlos Roque ^[3]

Afiliação do(s) autor(es)

^[1] Univ Campinas UNICAMP, Fac Tecnol, BR-13484332 Limeira, SP - Brazil

^[2] Univ Campinas UNICAMP, Fac Engn Alimentos, BR-13083682 Campinas, SP - Brazil

^[3] Univ Campinas UNICAMP, Inst Quim, CP 6154, BR-13084970 Campinas, SP - Brazil

• Tipo de documento: Artigo Científico
• Fonte: JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING; v. 6, n. 1, p. 1536-1545, FEB 2018.
• Citações Web of Science: 4

Resumo

The presence of surfactants in aquatic environment is a major public health concern. Recently, several methods have been developed to remove these compounds, among these are the adsorption processes. The great challenge of this technology is to achieve high removal capacities, fast adsorption and efficient adsorbent recoveries. The aim of our study was to synthesize GO and rGO and use them for non-ionic surfactant (TX-100) adsorption in consecutive cycles. Both nanomaterials were synthesized and characterized by several analyses including BET method for superficial area, XRD, Raman Spectroscopy, CP/MAS 13C NMR, TGA, FT-IR, XPS, SEM and TEM microscopies. The optimization of the adsorption process was performed by varying many parameters, including the experiment time, nanomaterials/surfactant ratio, temperature, pH and ultrasound irradiation. GO and rGO showed fast TX-100 adsorption, about 30 min to reach equilibrium. The experiments showed that the pH variation affects the removal efficiency for both nanomaterials with pH 6 being the optimized condition. The pseudo-second order kinetic model showed the best fit to the experimental data for both nanomaterials. The equilibrium data for GO and rGO were fitted to the Fowler-Guggenheim and the Langmuir models, respectively. The rGO was verified as the best adsorbent for TX-100 removal, suggesting that hydrophobic and pi-stacking interactions are dominant in the process. Besides the superior adsorption efficiency, rGO formed larger aggregates after TX-100 removal than GO, facilitating its separation from solution. Under optimized conditions, GO and rGO revealed superior removal capacities when compared to others adsorbents (1203 and 1683 mg/g, respectively). (AU)

• Processo FAPESP: 15/07033-7 - Preparação de nanomateriais derivados de óxido de grafeno, caracterização e sua aplicação na purificação de águas
• Beneficiário: Patricia Prediger
• Modalidade de apoio: Auxílio à Pesquisa - Regular
• Processo FAPESP: 15/07773-0 - Preparação de catalisadores de paládio suportados para a reação de heck-matsuda enantiosseletiva em fluxo contínuo
• Beneficiário: Rafael de Lima Oliveira
• Modalidade de apoio: Bolsas no Brasil - Pós-Doutorado