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(Referência obtida automaticamente do Web of Science, por meio da informação sobre o financiamento pela FAPESP e o número do processo correspondente, incluída na publicação pelos autores.)

Crystallization kinetics study of silver-doped germanium glasses

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Autor(es):
Fernandes, Roger Gomes [1] ; Valle, Paula Squinca [1] ; Franco, Douglas Faza [1] ; Nalin, Marcelo [1]
Número total de Autores: 4
Afiliação do(s) autor(es):
[1] Sao Paulo State Univ UNESP, Inst Chem, Araraquara - Brazil
Número total de Afiliações: 1
Tipo de documento: Artigo Científico
Fonte: Thermochimica Acta; v. 673, p. 40-52, MAR 2019.
Citações Web of Science: 1
Resumo

A series of germanium glasses in the systems (100-x){[}40GeO(2)-30Bi(2)O(3)-20PbO-10TiO(2)]-(x) AgCl with x = 0, 1, 3 and 5 (mol%) was prepared using the melt-quenching method and then characterized taking into account their crystallization kinetics mechanisms and microstructural analysis. Through Differential Scanning Calorimetry (DSC) performed in different linear heating rate programs, the experimental data obtained were based on non-isothermal models of phase transformation, since their versatility allows us to calculate kinetic parameters, for example, activation energy for crystallization (E-c) and Avrami index (n). Thus, it is possible to obtain information on the crystallization mechanism of these glasses. Independent of the model, the values of the Avrami index for each composition are the same, considering the uncertainty attributed to them. It is safe to affirm that bulk and surface nucleation contribute to the crystallization of compositions containing 0 and 1 mol% of AgCl, whereas internal and surface crystallization with one-dimensional growth occur in samples with 3 and 5 mol% of AgCl, respectively. These results were supported by a microstructural analysis from bulk samples that underwent non-isothermal heat treatment at different temperatures according to DSC crystallization peak. (AU)

Processo FAPESP: 13/07793-6 - CEPIV - Centro de Ensino, Pesquisa e Inovação em Vidros
Beneficiário:Edgar Dutra Zanotto
Linha de fomento: Auxílio à Pesquisa - Centros de Pesquisa, Inovação e Difusão - CEPIDs