Occurrence of PPCPs in a Brazilian water reservoir and their removal efficiency by ecological filtration

Autor(es)

Erba Pompei, Caroline Moco ^[1] ; Campos, Luiza Cintra ^[2] ; da Silva, Bianca Ferreira ^[3] ; Fogo, Jose Carlos ^[4] ; Vieira, Eny Maria ^[5]

Afiliação do(s) autor(es)

^[1] Univ Sao Paulo, Sao Carlos Sch Engn, Water Resources & Appl Ecol Ctr, Sao Carlos, SP - Brazil

^[2] UCL, Dept Civil Environm & Geomat Engn, Chadwick Bldg, Room GM11, Gower St, London WC1E 6BT - England

^[3] State Univ Julio de Mesquita Filho UNESP, Inst Chem, Araraquara, SP - Brazil

^[4] Univ Fed Sao Carlos, Dept Stat, Sao Carlos, SP - Brazil

^[5] Univ Sao Paulo, Sao Carlos Inst Chem, Dept Chem & Mol Phys, Sao Carlos, SP - Brazil

• Tipo de documento: Artigo Científico
• Fonte: Chemosphere; v. 226, p. 210-219, JUL 2019.
• Citações Web of Science: 3

Resumo

The presence of PPCPs (Pharmaceuticals and Personal Care Products) in water sources and drinking water has concerned researchers in recent times. This study was carried out to evaluate the occurrence of 6 PPCPs (namely paracetamol, diclofenac, naproxen, ibuprofen, benzophenone-3 and methylparaben) in the Lobo reservoir, their degradation products, and how efficiently they were removed by 22 ecological filters, considering individual and mixture of compounds. There were 3 spiking events of PPCPs (2 mu g L-1) in the ecological filter influents conducted with a lag period of 15 days between spikes. Water samples were collected from the influent and effluent of the filters at 3, 6 and 24 h after each spiking event. All target PPCPs were identified in the Lobo reservoir water in the range of mu g L-1. The personal care products were detected with 100% frequency in the samples, and in higher concentrations compared to the pharmaceuticals. Degradation products of diclofenac and benzophenone-3 were identified in the water samples. Results of this investigation show that ecological filtration was an effective process (70-99%) to remove 2 mu g L-1 of the selected PPCPs, and demonstrated that the filters were resilient to individual compounds and to their mixtures. (C) 2019 Elsevier Ltd. All rights reserved. (AU)

• Processo FAPESP: 11/21666-1 - Remoção de Produtos Farmacêuticos e de Cuidados Pessoais (PPCPs) por Filtro Ecológico
• Beneficiário: Caroline Moço Erba Pompei
• Modalidade de apoio: Bolsas no Brasil - Doutorado
• Processo FAPESP: 12/21981-7 - Remoção de produtos farmacêuticos e de cuidado pessoal (PPCPs) por filtro ecológico
• Beneficiário: Eny Maria Vieira
• Modalidade de apoio: Auxílio à Pesquisa - Regular
• Processo FAPESP: 08/10449-7 - Avaliação da ocorrência, toxicidade/genotoxicidade e processos para degradação de corantes em efluentes e águas superficiais
• Beneficiário: Maria Valnice Boldrin
• Modalidade de apoio: Auxílio à Pesquisa - Temático