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(Referência obtida automaticamente do Web of Science, por meio da informação sobre o financiamento pela FAPESP e o número do processo correspondente, incluída na publicação pelos autores.)

Surface interaction of CO2/H-2 mixture on mesoporous ZrO2: Effect of crystalline polymorph phases

Texto completo
Autor(es):
Marcos, Francielle C. F. [1, 2] ; Assaf, Jose M. [1] ; Giudici, Reinaldo [2] ; Assaf, Elisabete M. [3]
Número total de Autores: 4
Afiliação do(s) autor(es):
[1] Univ Fed Sao Carlos, Rod W Luiz, Km 235, BR-13565905 Sao Carlos, SP - Brazil
[2] Univ Sao Paulo, Escola Politecn, Av Prof Luciano Gualberto, T 3, 380, BR-05508010 Sao Paulo, SP - Brazil
[3] Univ Sao Paulo, Sao Carlos Inst Chem, Av Trabalhador Sao Carlense 400, BR-13560970 Sao Carlos, SP - Brazil
Número total de Afiliações: 3
Tipo de documento: Artigo Científico
Fonte: Applied Surface Science; v. 496, DEC 1 2019.
Citações Web of Science: 0
Resumo

A mesoporous zirconia (ZrO2) series was synthesized by reflux and hydrothermal methods using Pluronic (P-123) as a surfactant. Characterizations by XPD showed that the ZrO2 prepared via reflux consisted of only tetragonal crystalline phase when compared with that obtained by hydrothermal treatment, which was formed by tetragonal and monoclinic phases. The addition of the surfactant had a positive influence on the specific surface area and mesoporous structure ordering of ZrO2, regardless of the method of synthesis. The surface interaction of H-2/CO2 mixture with the ZrO2 samples exhibited some dissimilarity due to the unlike surface acidic-basic features of the tetragonal and monoclinic phases. In-situ DRIFTS experiments revealed that the species adsorbed on the zirconia prepared by the reflux method were bidentate bicarbonate, ionic bicarbonate, bidentate carbonate, and polydentate carbonate, whereas the adsorption on the zirconia prepared by refluxing method led to increased intensity of the broadband characteristic of bidentate carbonate and the appearance of two new bands typical of bidentate carbonate and bidentate bicarbonate. After subsequent switching off CO2, it was observed that the carbonate species (1550 cm(-1)) strongly interacted with the zirconia surface and required high energy amount to be desorbed, which was in good agreement with the CO2-TPD profile. This suggests that these carbonates are not active species when the reaction is carried out at 200 degrees C. (AU)

Processo FAPESP: 14/50279-4 - Brasil Research Centre for Gas Innovation
Beneficiário:Julio Romano Meneghini
Linha de fomento: Auxílio à Pesquisa - Programa Centros de Pesquisa em Engenharia
Processo FAPESP: 17/08293-8 - Projeto 14: síntese direta de metanol a partir de CO2
Beneficiário:Francielle Candian Firmino Marcos
Linha de fomento: Bolsas no Brasil - Pós-Doutorado