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(Referência obtida automaticamente do Web of Science, por meio da informação sobre o financiamento pela FAPESP e o número do processo correspondente, incluída na publicação pelos autores.)

Pd catalysts supported on different hydrophilic or hydrophobic carbonaceous substrate for furfural and 5-(hydroxymethyl)-furfural hydrogenation in water

Texto completo
Autor(es):
Silva, Wesley R. [1] ; Matsubara, Elaine Y. [1] ; Rosolen, Jose M. [1] ; Donate, Paulo M. [1] ; Gunnella, Roberto [2]
Número total de Autores: 5
Afiliação do(s) autor(es):
[1] Univ Sao Paulo, Fac Filosofia Ciencias & Letras Ribeirao Preto, Dept Quim, Ave Bandeirantes 3900, BR-14040901 Ribeirao Preto, SP - Brazil
[2] Univ Camerino, Phys Div, Via Madonna dele Carceri 9, I-62032 Camerino - Italy
Número total de Afiliações: 2
Tipo de documento: Artigo Científico
Fonte: MOLECULAR CATALYSIS; v. 504, MAR 2021.
Citações Web of Science: 0
Resumo

We hydrogenated furfural and 5-(hydroxymethyl)furfural (HMF) in water in a reaction catalyzed by Pd nanoparticles on carbonaceous materials with different morphology and hydrophobic degree. The different Pd catalysts were prepared by dipping the carbonaceous material into a Pd-0 micro-emulsion. The catalyst support affected the catalytic hydrogenation of furfural and HMF. By using micrometric active carbon (AC) combined with cup-stacked carbon nanotubes (CSCNTs) and Pd0/2+ nanoparticles (Pd), we obtained a micro/nanostructured material designated Pd/CSCNT-AC, which performed better than the other carbonaceous materials containing similar Pd nanoparticle loading. Pd/CSCNT-AC produced tetrahydrofurfuryl alcohol from furfural with excellent selectivity (>99 %). Unlike Pd on hybrophobic spheroid graphite or hydrophilic AC, Pd/CSCNT-AC hydrogenated both the C=O and C=C double bonds of furfural and catalyzed HMF hydrogenation at the C=O double bond more selectively: between 85 % and 99 % selectivity toward 2,5-dihydroxymethylfuran. We also investigated how temperature, hydrogen pressure, and reaction time affected HMF hydrogenation in water. Finally, Pd/CSCNT-AC was recycled several times without significant catalytic activity loss. (AU)

Processo FAPESP: 18/24680-4 - Síntese e modificações estruturais de derivados de butirolactonas para a obtenção de novos compostos de interesse biológico
Beneficiário:Paulo Marcos Donate
Modalidade de apoio: Auxílio à Pesquisa - Regular
Processo FAPESP: 17/04759-2 - Free-binder eletrodos para dispositivos de armazenagem/conversão de energia
Beneficiário:Jose Mauricio Rosolen
Modalidade de apoio: Auxílio à Pesquisa - Regular
Processo FAPESP: 16/04896-7 - Uso de processos multicomponentes na síntese de novos compostos de interesse farmacológico - Parte 2
Beneficiário:Paulo Marcos Donate
Modalidade de apoio: Auxílio à Pesquisa - Regular