Naphthenic Acids: Formation, Role in Emulsion Stability, and Recent Advances in Mass Spectrometry-Based Analytical Methods

Autor(es)

Facanali, Roselaine ^[1] ; Porto, Nathalia de A. ^[1] ; Crucello, Juliana ^[1] ; Carvalho, Rogerio M. ^[2] ; Vaz, Boniek G. ^[3] ; Hantao, Leandro W. ^[1]

Afiliação do(s) autor(es)

^[1] Univ Estadual Campinas, Inst Chem, BR-13083862 Campinas, SP - Brazil

^[2] Petrobras SA, Leopoldo Amer Miguez Mello Res & Dev Ctr, BR-20031912 Rio De Janeiro, RJ - Brazil

^[3] Univ Fed Goias, Inst Chem, BR-74690900 Goiania, Go - Brazil

• Tipo de documento: Artigo de Revisão
• Fonte: JOURNAL OF ANALYTICAL METHODS IN CHEMISTRY; v. 2021, DEC 17 2021.
• Citações Web of Science: 0

Resumo

Naphthenic acids (NAs) are compounds naturally present in most petroleum sources comprised of complex mixtures with a highly variable composition depending on their origin. Their occurrence in crude oil can cause severe corrosion problems and catalysts deactivation, decreasing oil quality and consequently impacting its productivity and economic value. NAs structures also allow them to behave as surfactants, causing the formation and stabilization of emulsions. In face of the ongoing challenge of treatment of water-in-oil (W/O) or oil-in-water (O/W) emulsions in the oil and gas industry, it is important to understand how NAs act in emulsified systems and which acids are present in the interface. Considering that, this review describes the properties of NAs, their role in the formation and stability of oil emulsions, and the modern analytical methods used for the qualitative analysis of such acids. (AU)

• Processo FAPESP: 20/01064-6 - Desenvolvimentos analíticos visando estudos com amostras reais do derrame de petróleo na costa litorânea de Pernambuco: simulações, caracterizações químicas e bioensaios de ecotoxicidade
• Beneficiário: Leandro Wang Hantao
• Modalidade de apoio: Auxílio à Pesquisa - Regular