Impact of severe plastic deformation on kinetics and thermodynamics of hydrogen storage in magnesium and its alloys

Autor(es):Mostrar menos -

Edalati, Kaveh ; Akiba, Etsuo ; Botta, Walter J. ; Estrin, Yuri ; Floriano, Ricardo ; Fruchart, Daniel ; Grosdidier, Thierry ; Horita, Zenji ; Huot, Jacques ; Li, Hai-Wen ; Lin, Huai-Jun ; Revesz, Adam ; Zehetbauer, Michael J.

• Tipo de documento: Artigo Científico
• Fonte: JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY; v. 146, p. 19-pg., 2023-05-20.

Resumo

Magnesium and its alloys are the most investigated materials for solid-state hydrogen storage in the form of metal hydrides, but there are still unresolved problems with the kinetics and thermodynam-ics of hydrogenation and dehydrogenation of this group of materials. Severe plastic deformation (SPD) methods, such as equal-channel angular pressing (ECAP), high-pressure torsion (HPT), intensive rolling, and fast forging, have been widely used to enhance the activation, air resistance, and hydrogena-tion/dehydrogenation kinetics of Mg-based hydrogen storage materials by introducing ultrafine/nanoscale grains and crystal lattice defects. These severely deformed materials, particularly in the presence of al-loying additives or second-phase nanoparticles, can show not only fast hydrogen absorption/desorption kinetics but also good cycling stability. It was shown that some materials that are apparently inert to hydrogen can absorb hydrogen after SPD processing. Moreover, the SPD methods were effectively used for hydrogen binding-energy engineering and synthesizing new magnesium alloys with low thermody-namic stability for reversible low/room-temperature hydrogen storage, such as nanoglasses, high-entropy alloys, and metastable phases including the high-pressure gamma-MgH2 polymorph. This work reviews recent advances in the development of Mg-based hydrogen storage materials by SPD processing and discusses their potential in future applications.(c) 2023 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology. (AU)

• Processo FAPESP: 13/05987-8 - Processamento e caracterização de ligas metálicas amorfas, metaestáveis e nano-estruturadas
• Beneficiário: Claudio Shyinti Kiminami
• Modalidade de apoio: Auxílio à Pesquisa - Temático
• Processo FAPESP: 22/01351-0 - Estudo dos mecanismos da reação metal-hidrogênio em ligas multicomponentes com estrutura de fase laves hexagonal C14
• Beneficiário: Ricardo Floriano
• Modalidade de apoio: Auxílio à Pesquisa - Regular