| Texto completo | |
| Autor(es): |
Camparotto, Natalia Gabriele
;
Paixa, Gustavo Rocha
;
Briao, Giani de Vargas
;
Oliveira, Rafael L.
;
Prediger, Patricia
;
Vieira, Melissa Gurgel Adeodato
Número total de Autores: 6
|
| Tipo de documento: | Artigo Científico |
| Fonte: | ENVIRONMENTAL TOXICOLOGY AND PHARMACOLOGY; v. 99, p. 14-pg., 2023-03-10. |
| Resumo | |
In this study, mesoporous doped-carbons were synthesized from sucrose, a natural source, boric acid and cyanamide as precursors, generating B- or N-doped carbon. These materials were characterized by FTIR, XRD, TGA, Raman, SEM, TEM, BET, and XPS, confirming the preparation of a tridimensional doped porous structure. B-MPC and N-MPC showed a high surface specific area above 1000 m(2)/g. The effect of B and N doping on mesoporous carbon was evaluated on the adsorption of emerging pollutants from water. Diclofenac sodium and paracetamol were used in adsorption assays, reaching removal capacities of 78 and 101 mg.g(-1), respectively. Kinetic and isothermal studies indicate the chemical nature of adsorption controlled by external and intraparticle diffusion and multilayer formation due to strong adsorbent/adsorbate interactions. DFT-based calculations and adsorption assays infer that the main attractive forces are hydrogen bonds and Lewis acid-base interactions. (AU) | |
| Processo FAPESP: | 19/07822-2 - Síntese de novos nanoadsorventes, suas caracterizações e aplicações na adsorção de poluentes em águas |
| Beneficiário: | Patricia Prediger |
| Modalidade de apoio: | Auxílio à Pesquisa - Regular |
| Processo FAPESP: | 19/11353-8 - Centro Brasileiro de Pesquisa em Água (BWRC) |
| Beneficiário: | Lauro Tatsuo Kubota |
| Modalidade de apoio: | Auxílio à Pesquisa - Programa Centros de Pesquisa Aplicada |