Monolayer Collapse Regulating Process of Adsorption-Desorption of Palladium Nanoparticles at Fatty Acid Monolayers at the Air-Water Interface

Autor(es)

Goto, Thiago E. ^[1] ; Lopez, Ricardo F. ^[1] ; Iost, Rodrigo M. ^[2] ; Crespilho, Frank N. ^[2] ; Caseli, Luciano ^[1]

Afiliação do(s) autor(es)

^[1] Univ Fed Sao Paulo, Inst Ciencias Ambientais Quim & Farmaceut, BR-09972270 Sao Paulo - Brazil

^[2] Univ Fed ABC, Ctr Ciencias Nat & Humanas, BR-09210170 Sao Paulo - Brazil

• Tipo de documento: Artigo Científico
• Fonte: Langmuir; v. 27, n. 6, p. 2667-2675, MAR 15 2011.
• Citações Web of Science: 4

Resumo

In this paper, we investigate the affinity of palladium nanoparticles, stabilized with glucose oxidase, for fatty acid monolayers at the air-water interface, exploiting the interaction between a planar system and spheroids coming from the aqueous subphase. A decrease of the monolayer collapse pressure in the second cycle of interface compression proved that the presence of the nanoparticles causes destabilization of the monolayer in a mechanism driven by the interpenetration of the enzyme into the bilayer/multilayer structure formed during collapse, which is not immediately reversible after monolayer expansion. Surface pressure and surface potential-area isotherms, as well as infrared spectroscopy {[}polarization modulation infrared reflection adsorption spectroscopy (PM-IRRAS)] and deposition onto solid plates as Langmuir-Blodgett (LB) films, were employed to construct a model in which the nanoparticle has a high affinity for the hydrophobic core of the structure formed after collapse, which provides a slow desorption rate from the interface after rnonolayer decompression. This may have important consequences on the interaction between the metallic particles and fatty acid monolayers, which implies the regulation of the multifunctional properties of the hybrid material. (AU)

• Processo FAPESP: 08/10851-0 - Filmes ultrafinos para a fabricação de biossensores e mimetização de biomembranas: aplicações na área ambiental e de saúde
• Beneficiário: Luciano Caseli
• Modalidade de apoio: Auxílio à Pesquisa - Jovens Pesquisadores
• Processo FAPESP: 10/07248-0 - Interações de polissacarídeos sulfatados em filmes finos organizados na interface ar-água
• Beneficiário: Ricardo de Felice Lopez
• Modalidade de apoio: Bolsas no Brasil - Iniciação Científica
• Processo FAPESP: 09/15558-1 - Interação entre biomoléculas e sistemas celulares com nanoestruturas 0D, 1D e 2D utilizando métodos eletroquímicos
• Beneficiário: Frank Nelson Crespilho
• Modalidade de apoio: Auxílio à Pesquisa - Regular