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(Referência obtida automaticamente do Web of Science, por meio da informação sobre o financiamento pela FAPESP e o número do processo correspondente, incluída na publicação pelos autores.)

Analysing Metals in Bottle-Grade Poly(ethylene terephthalate) by X-ray Fluorescence Spectrometry

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Autor(es):
Romao, Wanderson [1, 2] ; Franco, Marcos F. [1] ; Bueno, Maria Izabel M. S. [3] ; Eberlin, Marcos N. [2] ; De Paoli, Marco-Aurelio [1]
Número total de Autores: 5
Afiliação do(s) autor(es):
[1] Univ Estadual Campinas, Inst Quim, Lab Polimeros & Reciclagem, BR-13083970 Campinas, SP - Brazil
[2] Univ Estadual Campinas, Inst Quim, Lab ThoMSom Espectrometria Massas, BR-13083970 Campinas, SP - Brazil
[3] Univ Estadual Campinas, Inst Quim, Grp Espect Raios X, BR-13083970 Campinas, SP - Brazil
Número total de Afiliações: 3
Tipo de documento: Artigo Científico
Fonte: Journal of Applied Polymer Science; v. 117, n. 5, p. 2993-3000, SEP 5 2010.
Citações Web of Science: 13
Resumo

After a rigorous cleaning process, recycled food-grade poly(ethylene terephthalate) (PET), can be mixed with virgin PET resin in different concentrations and used for packaging of soft drinks. Therefore, it is important to have an experimental method to distinguish the presence of recycled polymer in a batch and to check its ``true quality.{''} One of the issues to be verified is the presence of inorganic contaminants due to the recycling process. X-ray fluorescence technique is one alternative for this kind of analysis. The results obtained in this work show that bottle-grade PET samples (PET-btg) are made either via direct esterification or by a transesterification process. Samples that were subjected to thermo-mechanical processings (superclean processing, PET-btg blends processed in our laboratory and soft drink PET packaging) present Fe K alpha emission lines with higher intensities than those presented by virgin bottle-grade PET. After applying principal component analysis, it can be concluded that Fe is an intrinsic contaminant after the recycling process, furnishing a way to indicate class separations of PET-btg. A calibration and validation partial least squares model was constructed to predict the weight percent of post-consumption bottle-grade PET in commercial PET samples. (C) 2010 Wiley Periodicals, Inc. J Appl Polym Sci 117: 2993-3000, 2010 (AU)

Processo FAPESP: 04/15084-6 - Materiais poliméricos de baixo impacto ambiental
Beneficiário:Marco-Aurelio de Paoli
Modalidade de apoio: Auxílio à Pesquisa - Temático
Processo FAPESP: 07/54023-0 - Desenvolvimento de metodologia para detectar a presença de pet-pós consumo em embalagens PET para alimentos
Beneficiário:Wanderson Romão
Modalidade de apoio: Bolsas no Brasil - Mestrado