Direct determination of sodium, potassium, chromium and vanadium in biodiesel fuel by tungsten coil atomic emission spectrometry

Autor(es)

Dancsak, Stacia E. ^[1] ; Silva, Sidnei G. ^[2] ; Nobrega, Joaquim A. ^[2] ; Jones, Bradley T. ^[1] ; Donati, George L. ^[1]

Afiliação do(s) autor(es)

^[1] Wake Forest Univ, Dept Chem, Winston Salem, NC 27109 - USA

^[2] Univ Fed Sao Carlos, Dept Chem, Grp Appl Instrumental Anal, BR-13560 Sao Carlos, SP - Brazil

• Tipo de documento: Artigo Científico
• Fonte: Analytica Chimica Acta; v. 806, p. 85-90, JAN 2 2014.
• Citações Web of Science: 18

Resumo

High levels of sodium and potassium can be present in biodiesel fuel and contribute to corrosion, reduced performance and shorter engine lifetime. On the other hand, trace amounts of chromium and vanadium can increase the emission of pollutants during biodiesel combustion. Sample viscosity, immiscibility with aqueous solutions and high carbon content can compromise biodiesel analyzes. In this work, tungsten filaments extracted from microscope light bulbs are used to successively decompose biodiesel's organic matrix, and atomize and excite the analytes to determine sodium, potassium, chromium and vanadium by tungsten coil atomic emission spectrometry (WCAES). No sample preparation other than simple dilution in methanol or ethanol is required. Direct analysis of 10-mu L sample aliquots using heating cycles with less than 150 s results in limits of detection (LOD) as low as 20, 70, 70 and 90 mu g kg(-1) for Na, K, Cr and V, respectively. The procedure's accuracy is checked by determining Na and K in a biodiesel reference sample and carrying out spike experiments for Cr and V. No statistically significant differences were observed between reference and determined values for all analytes at a 95% confidence level. The procedure was applied to three different biodiesel samples and concentrations between 6.08 and 95.6 mg kg(-1) for Na and K, and between 0.22 and 0.43 mg kg(-1) for V were obtained. The procedure is simple, fast and environmentally friendly. Small volumes of reagents, samples and gases are used and no residues are generated. Powers of detection are comparable to other traditional methods. (C) 2013 Elsevier B.V. All rights reserved. (AU)

• Processo FAPESP: 11/13288-7 - Desenvolvimento de sistemas de vaporização e atomização empregando radiação no infravermelho e filamento de tungstênio
• Beneficiário: Sidnei Gonçalves da Silva
• Modalidade de apoio: Bolsas no Brasil - Pós-Doutorado
• Processo FAPESP: 12/13647-0 - Desenvolvimento de procedimentos para determinação elementar por espectrometria de fluorescência atômica empregando filamento de tungstênio
• Beneficiário: Sidnei Gonçalves da Silva
• Modalidade de apoio: Bolsas no Exterior - Estágio de Pesquisa - Pós-Doutorado