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(Referência obtida automaticamente do Web of Science, por meio da informação sobre o financiamento pela FAPESP e o número do processo correspondente, incluída na publicação pelos autores.)

Effects of the host molecular dynamics on the photoemission temperature dependence of host/guest photoluminescent blends

Texto completo
Autor(es):
Menezes, Durval Bertoldo [1] ; Curcino da Silva, Silesia de Fatima [1] ; Akcelrud, Leni [2] ; Atvars, Teresa Dib Zambon [3] ; Balogh, Debora Terezia [4] ; Mascarenhas, Yvonne Primerano [4] ; Marletta, Alexandre [1] ; Tozoni, Jose Roberto [1]
Número total de Autores: 8
Afiliação do(s) autor(es):
[1] Univ Fed Uberlandia, Inst Phys, POB 593, BR-38400902 Uberlandia, MG - Brazil
[2] Univ Fed Parana, Paulo Scarpa Polymer Lab, POB 19081, BR-81531990 Curitiba, Parana - Brazil
[3] Univ Estadual Campinas, Inst Chem, POB 6154, BR-13084971 Sao Paulo - Brazil
[4] Univ Sao Paulo, Inst Phys Sao Carlos, POB 369, BR-13560970 Sao Paulo - Brazil
Número total de Afiliações: 4
Tipo de documento: Artigo Científico
Fonte: Polymer; v. 90, p. 132-137, MAY 4 2016.
Citações Web of Science: 5
Resumo

In the present paper, the photoemission temperature dependence of host/guest blends has been investigated. The polymers blend is composed by poly(n-alkyl metacrylate) (PnMA) as a host and poly {[}(9,9-dihexyl-9H-fluorene-2,7-diyl)-1,2-ethenediyl-1,4-phenylene-1,2-e thenediyl] (LaPPS16) as a guest. The PnMAs/LaPSS16 blends presented high homogeneity and photoemission temperature stability (T similar to 30-410 K). Moreover, the PnMA/LaPPS16 blends photoemission in function of sample temperature allowed access to the PnMA molecular relaxations temperatures. This was possible due to the strong interaction between the PnMA n-alkyl side groups and the LaPPS16 aliphatic groups. In addition, the blends films were characterized by Wide-angle X-ray Diffraction, optical absorbance, steady-state photoluminescence spectroscopy, Emission Ellipsometry, and Dynamic Mechanical Analysis. (C) 2016 Elsevier Ltd. All rights reserved. (AU)

Processo FAPESP: 13/16245-2 - Propriedades fotofísicas de filmes finos de polímeros conjugados
Beneficiário:Teresa Dib Zambon Atvars
Modalidade de apoio: Auxílio à Pesquisa - Regular