| Full text | |
| Author(s): |
Menezes, Durval Bertoldo
[1]
;
Curcino da Silva, Silesia de Fatima
[1]
;
Akcelrud, Leni
[2]
;
Atvars, Teresa Dib Zambon
[3]
;
Balogh, Debora Terezia
[4]
;
Mascarenhas, Yvonne Primerano
[4]
;
Marletta, Alexandre
[1]
;
Tozoni, Jose Roberto
[1]
Total Authors: 8
|
| Affiliation: | [1] Univ Fed Uberlandia, Inst Phys, POB 593, BR-38400902 Uberlandia, MG - Brazil
[2] Univ Fed Parana, Paulo Scarpa Polymer Lab, POB 19081, BR-81531990 Curitiba, Parana - Brazil
[3] Univ Estadual Campinas, Inst Chem, POB 6154, BR-13084971 Sao Paulo - Brazil
[4] Univ Sao Paulo, Inst Phys Sao Carlos, POB 369, BR-13560970 Sao Paulo - Brazil
Total Affiliations: 4
|
| Document type: | Journal article |
| Source: | Polymer; v. 90, p. 132-137, MAY 4 2016. |
| Web of Science Citations: | 5 |
| Abstract | |
In the present paper, the photoemission temperature dependence of host/guest blends has been investigated. The polymers blend is composed by poly(n-alkyl metacrylate) (PnMA) as a host and poly {[}(9,9-dihexyl-9H-fluorene-2,7-diyl)-1,2-ethenediyl-1,4-phenylene-1,2-e thenediyl] (LaPPS16) as a guest. The PnMAs/LaPSS16 blends presented high homogeneity and photoemission temperature stability (T similar to 30-410 K). Moreover, the PnMA/LaPPS16 blends photoemission in function of sample temperature allowed access to the PnMA molecular relaxations temperatures. This was possible due to the strong interaction between the PnMA n-alkyl side groups and the LaPPS16 aliphatic groups. In addition, the blends films were characterized by Wide-angle X-ray Diffraction, optical absorbance, steady-state photoluminescence spectroscopy, Emission Ellipsometry, and Dynamic Mechanical Analysis. (C) 2016 Elsevier Ltd. All rights reserved. (AU) | |
| FAPESP's process: | 13/16245-2 - Photophysical properties of thin films of conjugated polymers |
| Grantee: | Teresa Dib Zambon Atvars |
| Support Opportunities: | Regular Research Grants |