| Texto completo | |
| Autor(es): |
de Jesus, Jessica C.
;
Pires, Paulo A. R.
;
Mustafa, Rizwana
;
Riaz, Naheed
;
El Seoud, Omar A.
Número total de Autores: 5
|
| Tipo de documento: | Artigo Científico |
| Fonte: | RSC ADVANCES; v. 7, n. 26, p. 15952-15963, 2017. |
| Citações Web of Science: | 7 |
| Resumo | |
We used solvatochromic compounds to probe solvation in mixtures of water, W, and four ionic liquids (ILs), 1-R-3-methylimidazoliumX, where R = n-butyl or methoxyethyl and X = acetate and chloride; these are denoted as (C(4)MeImAc), (C(3)OMeImAc), (C(4)MeImCl), and (C(3)OMeImCl). Our aim was to investigate the effects on solvation when an ether linkage is substituted for a -CH2-group in the IL side chain. We used the solvatochromic probes 2,6-dichloro-4-(2,4,6-triphenylpyridinium-1-yl) phenolate (WB) and 5-nitroindoline, 1-methyl-5-nitroindoline to determine the solvent polarity, ET(WB), and Lewis basicity, SB, respectively. From UV-Vis spectral data, we calculated ET(WB) as a function of the water mole fraction (cW) at different temperatures; from 15 to 60 degrees C for WB in IL-acetate-W; 25 degrees C for SB and WB in IL-chloride- W. For all IL-W mixtures, the dependence of ET(WB) on cW is non-linear and, surprisingly, shows negligible dependence on the nature of the side chain. Values of the SB of IL-W were higher for C(4)MeImX-W than for C(3)OMeImX. A rationale for these results is the deactivation of the ether oxygen due to the formation of intramolecular hydrogen bonds with the hydrogens of the imidazolium ring. Our hypothesis is confirmed by quantum chemistry and molecular dynamics calculations (energy of the conformers and radial distribution functions), density, and H-1 NMR data (chemical shifts, line widths). We attributed the non-linear dependence of the solvatochromic parameters on cW to preferential solvation of the dyes. We treated ET(WB) data with a model that includes the formation of the complex solvent ILW. Equilibrium constants for solvent exchange in the solvation layer of WB were calculated; their values showed that IL-W is the most efficient solvent species present. (AU) | |
| Processo FAPESP: | 14/22136-4 - Uso de solventes verdes e suas misturas na otimização de processos químicos |
| Beneficiário: | Omar Abou El Seoud |
| Modalidade de apoio: | Auxílio à Pesquisa - Temático |
| Processo FAPESP: | 16/13932-7 - Solvatação em misturas binárias de líquidos iônicos-solventes moleculares: efeitos da composição das misturas, da temperatura e aplicação na dissolução de celulose |
| Beneficiário: | Jessica Carol de Jesus |
| Modalidade de apoio: | Bolsas no Brasil - Iniciação Científica |