Morphological, Structural, and Chemical Properties of Thermally Stable Ni-Nb2O5 for Catalytic Applications

Autor(es)

Leal, Glauco F. ^{[1, 2]} ; Barrett, Dean H. ^{[1, 3]} ; Carrer, Heloise ^[1] ; Figueroa, Santiago J. A. ^[1] ; Teixeira-Neto, Erico ^[4] ; Curvelo, Antonio Aprigio S. ^[2] ; Rodella, Cristiane B. ^[1]

Afiliação do(s) autor(es)

^[1] Brazilian Ctr Res Energy & Mat CNPEM, Brazilian Synchrotron Light Lab LNLS, BR-13083970 Campinas, SP - Brazil

^[2] Univ Sao Paulo, Inst Chem Sao Carlos, Dept Phys Chem, Av Trabalhador Sao Carlense 400, BR-13566590 Sao Carlos, SP - Brazil

^[3] Univ Witwatersrand, Sch Chem, Jorissen St, Johannesburg - South Africa

^[4] Brazilian Ctr Res Energy & Mat CNPEM, Brazilian Nanotechnol Natl Lab LNNano, BR-13083970 Campinas, SP - Brazil

• Tipo de documento: Artigo Científico
• Fonte: Journal of Physical Chemistry C; v. 123, n. 5, p. 3130-3143, FEB 7 2019.
• Citações Web of Science: 1

Resumo

Structural stability is a pivotal property required for Nb2O5 to be applied as a solid-acid catalyst in heterogeneous catalytic reactions. When combined with Ni, Nb2O5 produces cheap and active hydrogenation catalysts. Ni-Nb2O5 operates as a bifunctional catalyst and is being widely explored for various catalytic applications without, however, exploring its structural stability and its effects on catalytic activity and durability. Herein we studied two forms of niobia, one with nonuniform morphology and another comprising a nanorod morphology. Various selected Ni loadings were dispersed on the two supports via a deposition-precipitation method. Physical and chemical characterization revealed that morphological control in combination with a highly efficient Ni deposition method is key in producing a structurally stable Ni-Nb2O5 catalyst. High surface area and porosity as exhibited by the Nb2O5 nanorods, in the pseudohexagonal phase, combined with small, well-dispersed Ni particles, provide a structurally stable material up to 500 degrees C, with high acidity (Lewis and Bronsted acid sites). Moreover, the local and long-range order, characterized in situ XANES and XRD), determined the temperature limits for the optimization of metallic Ni particles in relation to the Nb2O5 structure. (AU)

• Processo FAPESP: 15/22711-1 - Síntese e caracterização de catalisadores de ni e co suportados em Nb2O5 para conversão de celulose
• Beneficiário: Heloise Carrer
• Modalidade de apoio: Bolsas no Brasil - Iniciação Científica