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(Referência obtida automaticamente do Web of Science, por meio da informação sobre o financiamento pela FAPESP e o número do processo correspondente, incluída na publicação pelos autores.)

Tourmaline in the Passagem de Mariana gold deposit (Brazil) revisited: major-element, trace-element and B-isotope constraints on metallogenesis

Texto completo
Autor(es):
Trumbull, R. B. [1] ; Garda, G. M. [2] ; Xavier, R. P. [3] ; Cavalcanti, J. A. D. [4] ; Codeco, M. S. [1]
Número total de Autores: 5
Afiliação do(s) autor(es):
[1] GFZ German Res Ctr Geosci, Potsdam - Germany
[2] Univ Sao Paulo, Inst Geociencias, Sao Paulo - Brazil
[3] Univ Estadual Campinas Unicamp, Inst Geociencias, Campinas, SP - Brazil
[4] Serv Geol Brasil CPRM, Belo Horizonte, MG - Brazil
Número total de Afiliações: 4
Tipo de documento: Artigo Científico
Fonte: MINERALIUM DEPOSITA; v. 54, n. 3, p. 395-414, MAR 2019.
Citações Web of Science: 4
Resumo

Tourmaline at Passagem de Mariana forms three associations: stratiform tourmalinite (T1), wall-rock alteration around quartz-sulfide veins (T2), and clusters within the veins (T3). The major-element composition of tourmaline is similar in all, with Mg/(Mg+Fe) from 0.59 to 0.83 (mean 0.69 +/- 0.03) and total Al contents from 6.2 to 6.6 atoms per formula unit (apfu). The Y-site Al (0.2-0.6apfu) is charge-balanced by the exchange NaMg(Al?)(-1). Tourmalinite type (T1) is unzoned, whereas T2 and T3 grains display increasing Ti and Ca from core to rim. In situ trace-element analyses of T1 grains were prohibited by grain size and inclusions. The T2 and T3 tourmaline have similar trace-element values, except higher concentrations of Zn, Cu, and Co in T3, which is consistent with its location in the mineralized veins. The B-11 values of T1 and T2 tourmaline range from -17.8 to -9.7 parts per thousand, with indistinguishable mean values (-13.9 +/- 1.9 and -13.8 +/- 1.6 parts per thousand, respectively), supporting field evidence that T1 tourmalinite is hydrothermal. The B-11 values of T3 tourmaline are about 5 parts per thousand higher (mean -8.9 +/- 1.3 parts per thousand), which we ascribe to depletion of B-10 in the vein fluid due to tourmalinization of wall rocks. This implies that the initial B-11 value of hydrothermal fluid was about -11 parts per thousand (for 400 degrees C and the T1-T2 mean B-11=-14 parts per thousand). This indicates a crustal boron source but is otherwise non-specific. Based on geological arguments, we favor a source in the Minas Supergroup metasedimentary units hosting the deposit. (AU)

Processo FAPESP: 05/56651-3 - Estudo comparativo da gênese dos turmalinitos e das rochas e veios de quartzo ricos em turmalina associados a mineralizações de ouro e metais-base no contexto do Quadrilátero Ferrífero (MG) e Faixa Ribeira (SP)
Beneficiário:Gianna Maria Garda
Modalidade de apoio: Auxílio à Pesquisa - Regular
Processo FAPESP: 07/53895-4 - Isotopia do boro em turmalina de turmalinitos e rochas e veios de quartzo ricos em turmalina do anticlinal de Mariana (MG) e cinturão Ribeira (SP), SE do Brasil
Beneficiário:Gianna Maria Garda
Modalidade de apoio: Bolsas no Exterior - Pesquisa