Fundamentals and new approaches to calibration in atomic spectrometry

Autor(es)

Donati, George L. ^[1] ; Amais, Renata S. ^[2]

Afiliação do(s) autor(es)

^[1] Wake Forest Univ, Dept Chem, Salem Hall, Box 7486, Winston Salem, NC 27109 - USA

^[2] Univ Estadual Campinas, Inst Chem, Spectrometry Sample Preparat & Mechanizat Grp GEP, POB 6154, BR-13083970 Campinas, SP - Brazil

• Tipo de documento: Artigo de Revisão
• Fonte: Journal of Analytical Atomic Spectrometry; v. 34, n. 12, p. 2353-2369, DEC 1 2019.
• Citações Web of Science: 1

Resumo

Despite efforts to develop calibration-free methods for atomic spectrometry, the most successful applications of quantitative instrumental techniques involve calibration. In this review paper, we discuss the principles and applications of both traditional and some recently described calibration methods as they are used in spectrochemical analysis. We particularly focus on the fundamentals, basic conditions and statistics of linear regression based on least-squares fitting, including the impact of normality and heteroscedasticity on accuracy. Advantages and limitations of the external standard calibration (EC), internal standardization (IS) and standard additions (SA) methods are critically discussed, as well as new calibration strategies such as interference standard (IFS), standard dilution analysis (SDA), multi-energy calibration (MEC), multi-isotope calibration (MICal), multispecies calibration (MSC) and multi-flow calibration (MFC). (AU)

• Processo FAPESP: 18/23478-7 - Avaliação qualitativa da distribuição elementar e bioimageamento através da ablação a laser e espectrometria de massa com plasma acoplado indutivamente (LA-ICP-MS) em anéis de árvores e espeleotemas
• Beneficiário: Renata Stábile Amais
• Modalidade de apoio: Bolsas no Brasil - Pós-Doutorado