Femtosecond-laser induced two-photon absorption of GaN and AlxGa1-xN thin films: Tuning the nonlinear optical response by alloying and doping

Autor(es)

Vivas, M. G. ^[1] ; Manoel, D. S. ^[2] ; Dipold, J. ^[2] ; Martins, R. J. ^[2] ; Fonseca, R. D. ^[3] ; Manglano-Clavero, I ^{[4, 5]} ; Margenfeld, C. ^{[4, 5]} ; Waag, A. ^{[4, 5]} ; Voss, T. ^{[4, 5]} ; Mendonca, C. R. ^[2]

Afiliação do(s) autor(es)

^[1] Univ Fed Alfenas, Lab Espectroscopia Opt & Foton, Pocos De Caldas, MG - Brazil

^[2] Univ Sao Paulo, Sao Carlos Inst Phys, Sao Carlos, SP - Brazil

^[3] Univ Popular Cesar, Dept Fis, Valledupar 2000004, Cesar - Colombia

^[4] Tech Univ Carolo Wilhelmina Braunschweig, Inst Semicond Technol, Braunschweig - Germany

^[5] Tech Univ Carolo Wilhelmina Braunschweig, Lab Emerging Nanometrol LENA, Braunschweig - Germany

• Tipo de documento: Artigo Científico
• Fonte: Journal of Alloys and Compounds; v. 825, JUN 5 2020.
• Citações Web of Science: 0

Resumo

Semiconductors thin films are the foundation of modern technology. While the nonlinear optical (NLO) properties of bulk semiconductors have been systematically studied in the last three decades, it is still a great challenge to obtain them for semiconductors thin films, as the high laser irradiance in NLO experiments tends to irreversibly damage the thin films. In addition, tuning the NLO response of semiconductor thin films by alloying and doping has not been explored yet. Here, we study the influence of the Aluminum content in AlxGa1-xN thin films and the n-type doping concentration in GaN thin films on their two-photon absorption (2PA) coefficients. For this, we investigate five different GaN-based thin films: an unintentionally doped one with no Al as a reference, two n-type doped GaN films with distinct concentrations of silicon impurities, and two AlxGa1-xN alloys with an aluminum content of 5.5% and 9.0%, respectively. The femtosecond 2PA spectra reveal that doping impurities reduce the non-linear coefficients (similar to 10%), while alloying with Al enhances the 2PA coefficient up to 30%. We use the model of Brandi and Araujo to determine Kane's energy parameter related to the transition matrix element for each sample and compare them with recent theoretical studies based on the k.p theory where an excellent agreement is found. (C) 2020 Elsevier B.V. All rights reserved. (AU)

• Processo FAPESP: 15/20032-0 - Estudo das Propriedades Ópticas Não Lineares e de Transporte de Carga de Moléculas Multiramificadas via Métodos de Química Quântica.
• Beneficiário: Daniel Luiz da Silva
• Modalidade de apoio: Auxílio à Pesquisa - Regular
• Processo FAPESP: 18/11283-7 - Fotônica não linear: espectroscopia e processamento avançado de materiais
• Beneficiário: Cleber Renato Mendonça
• Modalidade de apoio: Auxílio à Pesquisa - Temático