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Minasgeraisite-(Y) discredited as an ordered intermediate between datolite and hingganite-(Y)

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Autor(es):
Atencio, Daniel
Número total de Autores: 1
Tipo de documento: Artigo Científico
Fonte: MINERALOGICAL MAGAZINE; v. 87, n. 5, p. 3-pg., 2023-09-01.
Resumo

Minasgeraisite-(Y) is discredited on the basis of it being an ordered intermediate between datolite and hingganite-(Y) (IMA-CNMNC Proposal 23-F). An idealised formula is (Ca2Y2)2(Be2B2)Si4O16(OH)4, which corresponds to Ca2B2Si2O8(OH)2 (datolite) + Y2Be2Si2O8(OH)2 (hingganite-(Y)). The type material is rich in Bi, the Bi-richest portion yet discovered from the type locality is shown to be an intermediate member between datolite, hingganite-(Y) and a hypothetical end-member phase yet to be found of composition Bi2Be2Si2O8(OH)2. Minasgeraisite-(Y) has a different space group to datolite and hingganite-(Y). This lowering of symmetry to an acentric triclinic system is caused by different element occupancies on the A site of the gadolinite supergroup structure, which for minasgeraisite-(Y) becomes four individual sites. Such an order-disorder of elements is not considered as species-defining criteria despite the change in space group. Therefore, minasgeraisite-(Y) is discredited. (AU)

Processo FAPESP: 19/23498-0 - Mineralogia brasileira: caracterização de espécies minerais novas e raras
Beneficiário:Daniel Atencio
Modalidade de apoio: Auxílio à Pesquisa - Regular