Hydrotalcite Supported on Polycaprolactone:Poly(methyl methacrylate) Fiber Membranes for Chlorogenic Acid Removal

Autor(es)

Nascimento, Andressa Cristina de Almeida ; Malafatti, Joao Otavio Donizette ; Sierra e Silva, Maria Luiza Lopes ; Moreira, Ailton Jose ; Thomazi, Adriana Coatrini ; Quaranta, Simone ; Paris, Elaine Cristina

• Tipo de documento: Artigo Científico
• Fonte: WATER; v. 17, n. 7, p. 20-pg., 2025-03-22.

Resumo

Polyphenols are organic molecules extracted from various fruits, such as coffee and citrus, that possess biological activity and antioxidant properties. However, the presence of polyphenols in the environment is hazardous to water quality and living health. Among a variety of water remediation methods, adsorption remains a staple in the field. Therefore, this work aims to develop porous polycaprolactone: poly(methyl methacrylate) (PCL:PMMA) membranes as a support for hydrotalcite immobilization for the removal of chlorogenic acid polyphenol (CGA) from aqueous solutions. Due to the hydrophilic nature of hydrotalcite, the adsorbent was functionalized with hexadecyltrimethylammonium bromide (CTAB) to increase its affinity for CGA, resulting in a removal efficiency of approximately 96%. Composite fiber membranes were prepared by solution-blowing spinning with specific amounts of hydrotalcite added (i.e., 1 to 60 wt%). A 3:1 PCL:PMMA blend resulted in superior mechanical traction (0.8 MPa) and stress deformation (70%) compared to pure PCL (0.7 MPa and 37%) and PMMA (0.1 MPa and 5%) fibers. PCL:PMMA membranes with 60% LDH-CTAB exhibited CGA removal rates equal to 55% in the first cycle while maintaining the capacity to remove 30% of the polyphenol after five consecutive reuses. Removal rates up to 90% could also be achieved with an appropriate adsorbent dose (2 g L-1). Adsorption was found to follow pseudo-second-order kinetics and was adequately described by the Langmuir model, saturating LDH-CTAB active sites in four hours. PCL:PMMA:LDH-CTAB composites can be considered a potential alternative to support adsorbents for water remediation. (AU)

• Processo FAPESP: 22/06219-3 - Desenvolvendo e disseminando novas tecnologias para remediação ambiental de contaminantes emergentes
• Beneficiário: Ailton Jose Moreira
• Modalidade de apoio: Auxílio à Pesquisa - Projeto Geração
• Processo FAPESP: 23/03632-0 - Desenvolvimento de sistemas de sensores baseados em nanoestruturas de zeólita funcionalizada com porfirinas para detecção de polifenóis
• Beneficiário: João Otávio Donizette Malafatti
• Modalidade de apoio: Bolsas no Exterior - Estágio de Pesquisa - Pós-Doutorado
• Processo FAPESP: 23/07525-3 - Desenvolvendo e disseminando novas tecnologias para remediação ambiental de contaminantes emergentes
• Beneficiário: Ailton Jose Moreira
• Modalidade de apoio: Bolsas no Brasil - Projeto Geração
• Processo FAPESP: 21/14992-1 - Obtenção de membranas nanocompósitas de PCL/PMMA/zeólita para aplicação como sensor químico para detecção de resíduos de polifenóis da indústria cafeeira
• Beneficiário: João Otávio Donizette Malafatti
• Modalidade de apoio: Bolsas no Brasil - Pós-Doutorado