Diesel degradation in soil by fenton process

Autor(es)

Villa, Ricardo D. ^[1] ; Trovo, Alam G. ^[1] ; Pupo Nogueira, Raquel F. ^[1]

Afiliação do(s) autor(es)

^[1] Univ Estadual Paulista, UNESP, Inst Quim Araraquara, BR-14801970 Araraquara, SP - Brazil

• Tipo de documento: Artigo Científico
• Fonte: Journal of the Brazilian Chemical Society; v. 21, n. 6, p. 1088-1095, 2010.
• Citações Web of Science: 12

Resumo

This work reports the use of Fenton process for diesel degradation and addresses common aspects of real situations that can affect the soil remediation efficiency. It was observed that most of diesel hydrocarbons containing less than 14 carbon atoms were lost by volatilization prior to the treatment. About 80% degradation was achieved in a loam soil, while less than 20% was observed in a clay loam soil. The multiple additions of H2O2 resulted in 80% diesel degradation, while only 14% of diesel was degraded after a reaction time of 80 h using a single addition. The addition of soluble iron was essential to achieve high degradation levels. No significant increase in diesel degradation (t-test; P = 0.05) was observed using H2O2 dosages between 0.09 and 0.36 g g-1. Furthermore, the highest H2O2 dosage applied (0.36 g g-1) degraded around 87% of the organic matter originally present in the soil. (AU)

• Processo FAPESP: 05/00172-0 - Fotodegradação de fármacos por processos oxidativos avançados utilizando irradiação artificial e solar: identificação de intermediários
• Beneficiário: Alam Gustavo Trovó
• Modalidade de apoio: Bolsas no Brasil - Doutorado