Sulphate radical generation through interaction of peroxymonosulphate with Co(II) for in-line sample preparation aiming at spectrophotometric flow-based determination of phosphate and phosphite in fertilizers

Autor(es)

Crispino, Carla C. ^[1] ; Kamogawa, Marcos Y. ^[2] ; Ferreira, Jose R. ^{[1, 3]} ; Zagatto, Elias A. G. ^[1]

Afiliação do(s) autor(es)

^[1] Univ Sao Paulo, Ctr Nucl Energy Agr, Piracicaba, SP - Brazil

^[2] Univ Sao Paulo, Luiz de Queiroz Coll Agr, Piracicaba, SP - Brazil

^[3] Agr Secretary, Reg South Res Ctr, Piracicaba, SP - Brazil

• Tipo de documento: Artigo Científico
• Fonte: Talanta; v. 158, p. 270-275, SEP 1 2016.
• Citações Web of Science: 1

Resumo

An advanced oxidative process relying on the interaction of peroxymonosulphate and cobalt(II) was implemented for generating the sulphate radicals in flow analysis, in order to accomplish in-line sample preparation thus improving the spectrophotometric determination of phosphate and phosphite in liquid foliar fertilizers. To this end, a flow-batch system with a heated chamber was designed. The sample was handled twice, with and without the step of phosphite oxidation to phosphate, and the formed orthophosphate was quantified after interaction with the vanadate-molybdate reagent. Phosphite was determined as the difference in analytical signals corresponding to sample handling with and without the oxidation step. Influence of Co(II) on the peroxymonosulphate activation, reagent concentrations and added volumes, acidity, temperature and heating time were investigated like aiming at to improve analytical recovery and measurement repeatability, as well as the and system ruggedness. The 6.6-20.0 mg L-1 P2O5 standards were in-line prepared from a single stock solution. Detection limits were estimated as 0.8 and 0.1 mg L-1 for P2O5 and P-PO4. Twenty-four samples are were run per hour, and results are were in agreement with those obtained by the official procedure. (C) 2016 Elsevier B.V. All rights reserved. (AU)

• Processo FAPESP: 13/22927-9 - Processos oxidativos avançados na análise química em fluxo.
• Beneficiário: Carla Cripa Crispino Kamogawa
• Modalidade de apoio: Bolsas no Brasil - Pós-Doutorado
• Processo FAPESP: 11/23498-9 - Sistemas avançados de análises químicas em fluxo: aplicações nas áreas tecnológica, agronômica e ambiental
• Beneficiário: Elias Ayres Guidetti Zagatto
• Modalidade de apoio: Auxílio à Pesquisa - Temático