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(Referência obtida automaticamente do Web of Science, por meio da informação sobre o financiamento pela FAPESP e o número do processo correspondente, incluída na publicação pelos autores.)

The Ta-B system: Key experiments and thermodynamic modeling

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Autor(es):
Araujo Pinto da Silva, Antonio Augusto [1] ; Ferreira, Flavio [2] ; de Lima-Kuhn, Belmira Benedita [3] ; Coelho, Gilberto Carvalho [4] ; Nunes, Carlos Angelo [4] ; Vilasi, Pauline [5] ; Fiorani, Jean-Marc [6] ; David, Nicolas [6] ; Vilasi, Michel [6]
Número total de Autores: 9
Afiliação do(s) autor(es):
[1] Univ Fed Itajuba, Inst Engn Mecan, Itajuba, MG - Brazil
[2] Univ Fed Fluminense, Escola Engn Ind Met Volta Redonda, Volta Redonda, RJ - Brazil
[3] Univ Fed Rural Rio de Janeiro, Inst Tecnol, Seropedica, RJ - Brazil
[4] Univ Sao Paulo, Escola Engn Lorena, Lorena, SP - Brazil
[5] Univ Technol Belfort Montbeliard, Lab Etud & Recherches Mat, Proc & Surfaces, Montbeliard - France
[6] Univ Lorraine, Inst Jean Lamour, Vandoeuvre Les Nancy - France
Número total de Afiliações: 6
Tipo de documento: Artigo Científico
Fonte: CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY; v. 63, p. 107-115, DEC 2018.
Citações Web of Science: 3
Resumo

In the present work, the Ta-B system was thermodynamically optimized based on the CALPHAD method using data of liquidus temperatures, invariant transformations and enthalpy of formation from the literature as well as new experiments performed in our group. The phases Ta3B2, TaB(rt), Ta5B6, Ta3B4 were modeled as stoichiometric compounds. On the other hand, L (liquid), BCC, Ta2B, TaB(ht) and TaB2 were modeled as solution phases using the Compound Energy Formalism (CEF), with excess terms described by the Redlich-Kister polynomials. (beta B) was treated as a pure element without any Ta solubility. The present thermodynamic modeling is in good agreement with the experimental data. (AU)

Processo FAPESP: 00/11620-0 - Estudo experimental e calculo termodinamico do sistema tantalo-boro.
Beneficiário:Vanessa Motta Chad
Modalidade de apoio: Bolsas no Brasil - Mestrado