Degradation Kinetics of Landfill Leachate by Continuous-Flow Catalytic Ozonation

Autor(es)

de Brito, Renata Alves ^[1] ; Izario Filho, Helcio Jose ^[1] ; Aguiar, Leandro G. ^[1] ; Kondracki de Alcantara, Marco Aurelio ^[2] ; Siqueira, Adriano Francisco ^[1] ; Molgero da Ros, Patricia Caroline ^[1]

Afiliação do(s) autor(es)

^[1] Sao Paulo Univ USP, Engn Sch Lorena, Dept Chem, BR-12602810 Lorena, SP - Brazil

^[2] Sao Paulo Univ USP, Engn Sch Lorena, Dept Basic & Environm Sci, BR-12602810 Lorena, SP - Brazil

• Tipo de documento: Artigo Científico
• Fonte: Industrial & Engineering Chemistry Research; v. 58, n. 23, p. 9855-9863, JUN 12 2019.
• Citações Web of Science: 0

Resumo

Landfill leachate contains a variety of compounds, many of which are chemically and biologically recalcitrant. The aim of this study was to convert a batch/semicontinuous reactor into a continuous tubular reactor for catalytic ozonation of landfill leachate with Fe2+ and develop a kinetic model for the degradation of organic carbon in leachate. The reaction volume was kept constant throughout the experiments by controlling the inflow of air, ozone, and catalyst solution and the outflow of foam. The kinetic model revealed TOC scission rate constants ranging from 3.5 X 10(6) to 4.45 X 10(7) L mol(-1) s(-1) and showed good predictive capacity (R-2 = 0.9999). The use of a continuous reactor for catalytic ozonation and the kinetic model developed for the degradation of organic carbon in landfill leachate are innovations that can provide important technical information to support process scale up. For instance, the developed model was able to predict the amount of reagent and the operating conditions that are necessary to achieve a specific level of TOC removal, which is essential information to design a full-scale system for treating landfill leachate. (AU)

• Processo FAPESP: 11/06710-4 - Movimentação de cádmio e chumbo em colunas de solo devido à aplicação de chorume
• Beneficiário: Marco Aurélio Kondracki de Alcântara
• Modalidade de apoio: Auxílio à Pesquisa - Regular