THE VANADIUM REDOX FLOW BATTERY: AN ASYMPTOTIC PERSPECTIVE

Autor(es)

Vynnycky, M. ^{[1, 2]} ; Assuncao, M. ^[3]

Afiliação do(s) autor(es)

^[1] Univ Limerick, Dept Math & Stat, Limerick V94 T9PX - Ireland

^[2] KTH Royal Inst Technol, Dept Mat Sci & Engn, S-10044 Stockholm - Sweden

^[3] Univ Sao Paulo Sao Carlos, Inst Math & Comp Sci, Dept Appl Math & Stat, BR-13560970 Sao Carlos, SP - Brazil

• Tipo de documento: Artigo Científico
• Fonte: SIAM JOURNAL ON APPLIED MATHEMATICS; v. 79, n. 4, p. 1147-1172, 2019.
• Citações Web of Science: 0

Resumo

Asymptotic methods are used to analyze a time-dependent two-dimensional (2D) model for the operation of a vanadium redox flow battery-an energy storage technology that has attracted much attention recently. The model takes into account mass, momentum, and charge conservation involving a total of seven ionic species in two porous electrodes that are separated by a proton exchange membrane and attached to external recirculating tanks. In particular, we demonstrate a self-consistent asymptotic reduction of the original model. From this, we identify the presence of concentration boundary layers in each porous electrode at its interface with the membrane, and are able to explain the linear evolution in time of the inlet concentrations of the reacting ionic species-an assumption used in earlier models but never justified. The results of the asymptotic model, which ultimately requires only the numerical solution of four coupled nonlinear ordinary differential equations, are found to compare favorably with those of the original 2D transient problem, which involves 11 coupled nonlinear partial differential equations and two algebraic relations. The solution of the fully reduced asymptotic model is found to require around 300 times less computational time than that of the original model. (AU)

• Processo FAPESP: 13/15875-2 - Modelagem matemática de baterias redox de vanádio
• Beneficiário: Milton de Oliveira Assunção Junior
• Modalidade de apoio: Bolsas no Brasil - Mestrado
• Processo FAPESP: 14/03787-4 - Modelagem matemática de baterias redox de vanádio
• Beneficiário: Milton de Oliveira Assunção Junior
• Modalidade de apoio: Bolsas no Exterior - Estágio de Pesquisa - Mestrado
• Processo FAPESP: 18/07643-8 - Matemática industrial e técnicas assintóticas
• Beneficiário: José Alberto Cuminato
• Modalidade de apoio: Auxílio à Pesquisa - Pesquisador Visitante - Internacional