Lanthanum biosorption using sericin/alginate particles crosslinked by poly (vinyl alcohol): Kinetic, cation exchange, and desorption studies

Autor(es)

da Costa, Talles Barcelos ^[1] ; Carlos da Silva, Meuris Gurgel ^[1] ; Adeodato Vieira, Melissa Gurgel ^[1]

Afiliação do(s) autor(es)

^[1] Univ Estadual Campinas, Sch Chem Engn, Albert Einstein Ave, BR-13083852 Campinas - Brazil

• Tipo de documento: Artigo Científico
• Fonte: JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING; v. 9, n. 4 AUG 2021.
• Citações Web of Science: 0

Resumo

Nowadays, lanthanum removal from wastewater has received attention due to its importance in various industrial applications. Biosorption has been considered a promising process for lanthanum removal from secondary sources. This study aimed to evaluate the use of sericin/alginate/poly(vinyl alcohol) (SAPVA) particles for lanthanum biosorption in batch system. The effect of pH on the biosorption of lanthanum showed that both lanthanum-uptake (0.103 mol/kg) and calcium-release (0.155 mol/kg) reach a maximum at equilibrium pH 5.22. Biosorption kinetics was carried in three lanthanum initial concentrations (0.0005, 0.0011, and 0.0017 mol/dm(3)). The results revealed that the equilibration time was reached between 210 and 450 min and biosorption capacity at equilibrium between 0.050 and 0.152 mol/kg. The kinetic followed the pseudo-second order model and the external diffusion was the main limiting step. Evaluation of cation exchange mechanism showed that the lanthanum biosorption is related to a stoichiometric reaction (2:3 ratio) between calcium and lanthanum. Calcium nitrate under acidic conditions was able to retrieve lanthanum biosorbed in the particles with high efficiency (96.07 +/- 2.02%). Regeneration kinetics showed a longer equilibration time (630 min) and lower biosorption capacity at equilibrium (0.138 mol/kg) for the lanthanum initial concentration of 0.0015 mol/dm(3). In this case, the experimental kinetic profile of calcium released throughout the lanthanum biosorption was not stoichiometric. Characterization analyzes suggest that the main mechanism involved in lanthanum capture and calcium release was cation exchange between functional groups on the biosorbent particles and lanthanum. Thus, SAPVA particles are a promising biosorbent for lanthanum removal from aqueous solutions. (AU)

• Processo FAPESP: 17/18236-1 - Recuperação de íons metálicos nobres e íons terras-raras presentes em soluções aquosas por bioadsorção em partículas de blenda de sericina e alginato
• Beneficiário: Melissa Gurgel Adeodato Vieira
• Modalidade de apoio: Auxílio à Pesquisa - Regular
• Processo FAPESP: 19/11353-8 - Centro Brasileiro de Pesquisa em Água (BWRC)
• Beneficiário: Lauro Tatsuo Kubota
• Modalidade de apoio: Auxílio à Pesquisa - Programa Centros de Pesquisa em Engenharia