Reusable and efficient clay material for the fixed-bed neodymium recovery

Autor(es)

Briao, Giani de Vargas ; Carlos da Silva, Meuris Gurgel ; Adeodato Vieira, Melissa Gurgel

• Tipo de documento: Artigo Científico
• Fonte: SUSTAINABLE CHEMISTRY AND PHARMACY; v. 25, p. 14-pg., 2022-04-01.

Resumo

Neodymium is an essential resource for the future development of clean energy. Its future supply is a global concern motivating the application of different adsorbent materials to recover neodymium from secondary sources. However, there is a lack of studies of adsorption with scale-up potential. This work aims to recuperate neodymium from aqueous solution through dynamic adsorption in a fixed-bed of expanded vermiculite, an abundant clay mineral with excellent adsorbent properties. For that, the flow rate and concentration optimization, mathematical modeling; cycles of adsorption and desorption; and the extensive characterization of the regenerated adsorbent matrix were carried out. The main findings of the study are the column high adsorption capacity 0.40 mmol/g; the effective modeling of the column by Thomas and DualSD model, being useful for scale-up purposes; the constant bed efficiency along with the cycles and the well succeed neodymium recovery (96% in the third cycle) and concentration (28.4 times). Besides that, the structural composition was maintained, attesting to the physical and chemical stability of the material. Thus, the neodymium continuous recovery from aqueous solution through successive cycles of adsorption and desorption on an expanded vermiculite fixed-bed has high potential for scale-up and rare earth rich wastewater treatment studies. (AU)

• Processo FAPESP: 17/18236-1 - Recuperação de íons metálicos nobres e íons terras-raras presentes em soluções aquosas por bioadsorção em partículas de blenda de sericina e alginato
• Beneficiário: Melissa Gurgel Adeodato Vieira
• Modalidade de apoio: Auxílio à Pesquisa - Regular
• Processo FAPESP: 19/11353-8 - Centro Brasileiro de Pesquisa em Água (BWRC)
• Beneficiário: Lauro Tatsuo Kubota
• Modalidade de apoio: Auxílio à Pesquisa - Programa Centros de Pesquisa em Engenharia