Photochemical Reactions of Sulfur Ylides

Autor(es)

Echemendia, Radell ; Capellaro, Kaue C. ; Burtoloso, Antonio C. B.

• Tipo de documento: Artigo Científico
• Fonte: CURRENT ORGANIC CHEMISTRY; v. 28, n. 13, p. 13-pg., 2024-01-01.

Resumo

Photochemical reactions offer unparalleled opportunities to access elusive chemical pathways and develop innovative strategies for constructing complex molecules. Within organic synthesis, photochemical reactions have become indispensable tools for accessing complex molecular structures, such as pharmaceuticals and natural products. The ability of sulfur ylides to participate in these diverse processes has made them indispensable tools in the synthetic chemist's toolbox. The use of sulfur ylides in photochemical transformations has garnered significant attention in the synthetic organic chemistry community, and they serve as powerful intermediates in several chemical transformations. This review article presents a comprehensive overview of the photochemical reactions mediated by sulfur ylides. Herein, we describe the key aspects of the reactivity of sulfur ylides in the presence of light. The reactivity of these compounds can be classified into three categories: sulfur ylides as energy acceptors, as electron donors, and as trapping reagents. (AU)

• Processo FAPESP: 19/12300-5 - Síntese de butenolídeos e butirolactamas a partir de reações entre ilídeos de enxofre e compostos diazocarbonílicos
• Beneficiário: Radell Echemendía Pérez
• Modalidade de apoio: Bolsas no Brasil - Pós-Doutorado
• Processo FAPESP: 22/09140-9 - Transformação de ilídeos de sulfoxônio e compostos de iodo hipervalente
• Beneficiário: Radell Echemendía Pérez
• Modalidade de apoio: Bolsas no Exterior - Estágio de Pesquisa - Pós-Doutorado
• Processo FAPESP: 23/02675-7 - Novas metodologias para formação de ligações C-C a partir de ilídeos sulfoxônios
• Beneficiário: Antonio Carlos Bender Burtoloso
• Modalidade de apoio: Auxílio à Pesquisa - Regular