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(Referência obtida automaticamente do Web of Science, por meio da informação sobre o financiamento pela FAPESP e o número do processo correspondente, incluída na publicação pelos autores.)

Study of the Fusel Oil Distillation Process

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Autor(es):
Ferreira, Marcela C. [1] ; Meirelles, Antonio J. A. [1] ; Batista, Eduardo A. C. [1]
Número total de Autores: 3
Afiliação do(s) autor(es):
[1] Univ Estadual Campinas, ExTrAE, Lab Extract Appl Thermodynam & Equilibrium, Dept Food Engn, Fac Food Engn, UNICAMP, BR-13083862 Campinas, SP - Brazil
Número total de Afiliações: 1
Tipo de documento: Artigo Científico
Fonte: Industrial & Engineering Chemistry Research; v. 52, n. 6, p. 2336-2351, FEB 13 2013.
Citações Web of Science: 31
Resumo

Fusel oil is a byproduct obtained from bioethanol distilleries, composed of a mixture of higher alcohols such as isoamyl alcohol, isobutyl alcohol, and others. This study aimed to evaluate the industrial distillation process of fusel oil to obtain isoamyl alcohol using the Aspen Plus simulator, considering fusel oil as a mixture of nine components. Fusel oil samples collected in Brazilian industrial mills were analyzed by gas chromatography. An investigation of phase equilibrium (vapor liquid equilibrium and liquid-liquid equilibrium) was carried out for the components involved in this mixture. Three configurations for the fusel oil separation process were proposed. The best design with minimum total annual cost (TAC) resulted in a recovery of 99.53% of isoamyl alcohol of product containing the isomers isoamyl alcohol (0.818 w/w) and active amyl alcohol (0.178 w/w). Dynamic control of this configuration was investigated, and the results show that reasonable control performance can be achieved. (AU)

Processo FAPESP: 08/56258-8 - Phase equilibrium and purification processes in the production of biofuels and biocompounds
Beneficiário:Antonio José de Almeida Meirelles
Modalidade de apoio: Auxílio à Pesquisa - Programa BIOEN - Temático