Phase equilibrium and purification processes in the production of biofuels and biocompounds

• Processo: 08/56258-8
• Modalidade de apoio: Auxílio à Pesquisa - Programa BIOEN - Temático
• Vigência: 01 de agosto de 2009 - 31 de março de 2014
• Área do conhecimento: Ciências Agrárias - Ciência e Tecnologia de Alimentos - Engenharia de Alimentos
• Convênio/Acordo: CNPq - Pronex
• Pesquisador responsável: Antonio José de Almeida Meirelles
• Beneficiário: Antonio José de Almeida Meirelles
• Instituição Sede: Faculdade de Engenharia de Alimentos (FEA). Universidade Estadual de Campinas (UNICAMP). Campinas , SP, Brasil
• Pesquisadores principais: Pedro de Alcântara Pessôa Filho
• Auxílios(s) vinculado(s): 12/21765-2 - Visita do Prof. Dr. Christian Stevens à Faculdade de Engenharia de Alimentos/UNICAMP, AV.EXT; 12/00868-8 - 34th Symposium on Biotechnology for Fuels and Chemicals, AR.EXT
• Bolsa(s) vinculada(s): 13/11868-1 - Equilíbrio líquido-líquido em sistemas-modelos formados por óleo vegetal + aldeído + etanol anidro a 25 ºC, BP.MS; 13/12428-5 - Refino físico de óleos vegetais: estudo das cinéticas e mecanismos envolvidos no processo, BP.PD; 12/13486-6 - Determinação de dados de equilíbrio líquido-líquido e cinética reacional de óleos vegetais na produção de biodiesel etílico, BP.IC; + mais bolsas vinculadas 12/05138-8 - Influência de acilgliceróis parciais nas propriedades físicas de óleo vegetal e biodiesel: determinação experimental e avaliação de métodos preditivos, BP.IC; 12/04792-6 - Equilíbrio líquido-líquido e sólido-líquido de sistemas graxos e alcoólicos, BP.TT; 10/12856-9 - Equilíbrio líquido-líquido de sistemas contendo óleo de soja, ácido linoleico, etanol, água, e compostos minoritários (tocoferóis e tocotrienóis), BP.IC; 10/11150-5 - Equilíbrio líquido-líquido e desodorização de sistemas graxos, BP.TT; 10/02899-2 - Equilíbrio líquido-líquido em sistemas envolvendo biocombustíveis: água + 2,5-dimetilfurano + solvente, BP.MS; 10/05689-9 - Equilíbrio sólido líquido misturas binárias de álcoois graxos saturados + ácidos graxos saturados através da calorimetria exploratória diferencial, BP.IC; 09/11083-9 - Viscosidades de misturas envolvendo álcoois de cadeia curta e compostos graxos: obtenção de novos parâmetros para o modelo unifac-visco, BP.MS; 10/00853-5 - Equilíbrio líquido-líquido e desodorização de sistemas graxos, BP.TT; 10/00848-1 - Equilíbrio sólido-líquido e líquido vapor de sistemas graxos e alcoólicos, BP.TT; 08/08706-1 - Determinação Experimental de Dados de Equilíbrio Líquido-Vapor de Misturas Binárias de Ésteres Graxos Etílicos e Ácidos Graxos através da Calorimetria Diferencial Exploratória, BP.DR; 08/09502-0 - Estudo detalhado do equilíbrio sólido-líquido de misturas de álcoois graxos com ácidos graxos, BP.PD - menos bolsas vinculadas
• Assunto(s): Bioenergia Biocombustíveis Etanol Biodiesel Simulação de processos
• Palavra(s)-Chave do Pesquisador: Biocompounds | Biodiesel | Bioethanol | Distillation | Phase Equilibrium | Process Simulation
• Publicação FAPESP: https://media.fapesp.br/bv/uploads/publicacoes/pasta_bioen_jun2012_32.pdf

Resumo

This project aims to optimize the purification processes used in the production of biofuels and to enhance the added value of byproducts generated during such processes. In the case of bioethanol, the distillation process will be investigated taking into account minor components relevant for product quality, according to standards fixed by the legislation for biofuels and the requirements of the raw materials for the chemical, pharmaceutical, cosmetics and food industries. The configurations of distillation columns currently in use in sugar mills will be investigated by experimental means in the industrial units and by process simulation. A comprehensive investigation of the phase equilibrium of wine will be carried out, taking into account a complete set of minor components. New and innovative configurations for distillation columns will be proposed, aiming at better product quality, equipment flexibility, higher ethanol recovery, lower energy consumption and better byproduct quality. Such configurations will be further tested for concentrating the bioethanol obtained from wine with a high alcohol content and from cellulosic residues. In the case of ethylic biodiesel, a comprehensive investigation of the different types of phase equilibrium occurring throughout the whole production process will be carried out. The use of ethylic alcohol as a solvent for extracting vegetable oils from seeds and grains, and for deacidifying crude oils by liquid-liquid extraction, as well as its use as a reactant in biodiesel production will be studied, with the purpose of integrating biodiesel and bioethanol productions. The optimization of the whole production process, including the oil extraction and deacidification, biodiesel reaction and purification, will be performed by simulation. In the case of biocompounds, strategies for enhancing the value of byproducts generated during the production of biofuels will be investigated. For instance, the fractionation of higher alcohols generated as a sidestream during the distillation of bioethanol, the use of glycerol in the production of surfactants and emulsifiers, the recovery of nutraceuticals from edible oils, and the formulation and fractionation of fatty mixtures based on solid-liquid equilibrium data. (AU)

Publicações científicas

(58)

(Referências obtidas automaticamente do Web of Science e do SciELO, por meio da informação sobre o financiamento pela FAPESP e o número do processo correspondente, incluída na publicação pelos autores)

SHIOZAWA, SIMONE; MEIRELLES, ANTONIO J. A.; BATISTA, EDUARDO A. C.. Liquid-liquid equilibrium data for systems important in biodiesel production, involving vegetable oils plus ethyl esters plus monoacylglycerols and diacylglycerols plus anhydrous ethanol, at 303.15 and 318.15 K. FUEL, v. 180, p. 332-342, SEP 15 2016. (08/56258-8)

DEBONI, TAIANA M.; CUEVAS, MAITE S.; MIELKE NETO, PAULO; MOTA, RAFAEL V.; DAMASCENO, FABIOLLA S.; MELLER DA SILVA, LUIZA HELENA; RODRIGUES, CHRISTIANNE E. C.; MEIRELLES, ANTONIO J. A.. Deacidification of Soybean Oil by Ion Exchange. Food and Bioprocess Technology, v. 6, n. 12, p. 3335-3344, DEC 2013. (09/54137-1, 08/56258-8)

ROBUSTILLO, MARIA DOLORES; BARBOSA, DEISE FERNANDA; DE ALMEIDA MEIRELLES, ANTONIO JOSE; PESSOA FILHO, PEDRO DE ALCANTARA. Solid-liquid equilibrium in ternary mixtures of ethyl laurate, ethyl palmitate and ethyl stearate. Fluid Phase Equilibria, v. 358, p. 272-281, NOV 25 2013. (10/18355-1, 08/56258-8)

BATISTA, FABIO R. M.; FOLLEGATTI-ROMERO, LUIS A.; MEIRELLES, ANTONIO J. A.. A new distillation plant for neutral alcohol production. Separation and Purification Technology, v. 118, p. 784-793, OCT 30 2013. (09/54137-1, 12/08792-0, 08/56258-8)

BASSO, RODRIGO C.; MEIRELLES, ANTONIO J. A.; BATISTA, EDUARDO A. C.. Biodiesel Produced by Ethanolysis: Melting Profile, Densities, and Viscosities. ENERGY & FUELS, v. 27, n. 10, p. 5907-5914, OCT 2013. (08/56258-8)

SAMPAIO, KLICIA A.; AYALA, JOSE V.; SILVA, SIMONE M.; CERIANI, ROBERTA; VERHE, ROLAND; MEIRELLES, ANTONIO J. A.. Thermal Degradation Kinetics of Carotenoids in Palm Oil. JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, v. 90, n. 2, p. 191-198, FEB 2013. (10/16634-0, 09/54137-1, 08/56258-8)

BASSO, RODRIGO CORREA; MIYAKE, FABIO HIDEKI; DE ALMEIDA MEIRELLES, ANTONIO JOSE; CALDAS BATISTA, EDUARDO AUGUSTO. Liquid-liquid equilibrium data and thermodynamic modeling, at T/K=298.2, in the washing step of ethyl biodiesel production from crambe, fodder radish and macauba pulp oils. FUEL, v. 117, n. A, p. 590-597, JAN 2014. (08/56258-8)

DALMOLIN, IREDE; RIGO, ALINE A.; CORAZZA, MARCOS L.; NDIAYE, PAPA M.; MEIRELES, M. ANGELA A.; BATISTA, EDUARDO A. C.; VLADIMIR OLIVEIRA, J.. Phase behaviour and thermodynamic modelling for the system (grape seed oil plus carbon dioxide plus ethanol) at high pressures. JOURNAL OF CHEMICAL THERMODYNAMICS, v. 68, p. 71-74, JAN 2014. (08/56258-8)

CUEVAS, MAITE S.; DE SOUZA, PATRICIA T.; DA COSTA RODRIGUES, CHRISTIANNE E.; MEIRELLES, ANTONIO J. A.. Quantification and Determination of Composition of Steryl Ferulates in Refined Rice Bran Oils Using an UPLC-MS Method. JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, v. 94, n. 3, p. 375-385, MAR 2017. (09/54137-1, 15/07370-3, 08/56258-8, 14/09446-4, 14/21252-0)

MAZUTTI, MARCIO A.; VOLL, FERNANDO A. P.; CARDOZO-FILHO, LUCIO; CORAZZA, MARCOS L.; LANZA, MARCELO; PRIAMO, WAGNER L.; VLADIMIR OLIVEIRA, J.. Thermophysical properties of biodiesel and related systems: (Liquid plus liquid) equilibrium data for castor oil biodiesel. JOURNAL OF CHEMICAL THERMODYNAMICS, v. 62, p. 17-26, JUL 2013. (08/56258-8)

CUEVAS, MAIT S.; DEBONI, TAIANA M.; MIELKE NETO, PAULO; DAMASCENO, FABIOLLA S.; MOTA, RAFAEL V.; DA SILVA, LUIZA H. M.; RODRIGUES, CHRISTIANNE E. C.; MEIRELLES, ANTONIO J. A.. Using a Strong Anion-Exchange Resin to Deacidify Red Palm Oil. JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, v. 90, n. 10, p. 1589-1597, OCT 2013. (09/54137-1, 08/56258-8)

BASSO, R. C.; MEIRELLES, A. J. DE A.; BATISTA, E. A. C.. EXPERIMENTAL DATA, THERMODYNAMIC MODELING AND SENSITIVITY ANALYSES FOR THE PURIFICATION STEPS OF ETHYL BIODIESEL FROM FODDER RADISH OIL PRODUCTION. Brazilian Journal of Chemical Engineering, v. 34, n. 1, p. 341-353, JAN-MAR 2017. (08/56258-8)

CARARETO, NATALIA D. D.; COSTA, MARIANA C.; MEIRELLES, ANTONIO J. A.; PAULY, J.. High pressure solid-liquid equilibrium of fatty acid ethyl esters binary systems. Fluid Phase Equilibria, v. 382, p. 158-163, NOV 25 2014. (08/09502-0, 12/05027-1, 08/56258-8)

FERREIRA, MARCELA CRAVO; BESSA, LARISSA C. B. A.; SHIOZAWA, SIMONE; MEIRELLES, ANTONIO J. A.; CALDAS BATISTA, EDUARDO AUGUSTO. Liquid-liquid equilibrium of systems containing triacylglycerols (canola and corn oils), diacylglycerols, monoacylglycerols, fatty acids, ester and ethanol at T/K=303.15 and 318.15. Fluid Phase Equilibria, v. 404, p. 32-41, OCT 25 2015. (09/54137-1, 08/56258-8)

MAXIMO, GUILHERME J.; COSTA, MARIANA C.; COUTINHO, JOAO A. P.; MEIRELLES, ANTONIO J. A.. Trends and demands in the solid-liquid equilibrium of lipidic mixtures. RSC ADVANCES, v. 4, n. 60, p. 31840-31850, 2014. (12/05027-1, 08/56258-8)

CARARETO, NATALIA D. D.; CASTAGNARO, THAMIRES; COSTA, MARIANA C.; MEIRELLES, ANTONIO J. A.. The binary (solid plus liquid) phase diagrams of (caprylic or capric acid) + (1-octanol or 1-decanol). JOURNAL OF CHEMICAL THERMODYNAMICS, v. 78, p. 99-108, NOV 2014. (08/09502-0, 12/05027-1, 08/56258-8)

BESSA, LARISSA C. B. A.; FERREIRA, MARCELA C.; SHIOZAWA, SIMONE; BATISTA, EDUARDO A. C.; MEIRELLES, ANTONIO J. A.. (Liquid plus liquid) equilibrium of systems involved in the stepwise ethanolysis of vegetable oils. JOURNAL OF CHEMICAL THERMODYNAMICS, v. 89, p. 148-158, OCT 2015. (09/54137-1, 08/56258-8)

MAXIMO, GUILHERME J.; SANTOS, RICARDO J. B. N.; LOPES-DA-SIVA, JOSE A.; COSTA, MARIANA C.; MEIRELLES, ANTONIO J. A.; COUTINHO, JOAO A. P.. Lipidic Protic Ionic Liquid Crystals. ACS SUSTAINABLE CHEMISTRY & ENGINEERING, v. 2, n. 4, p. 672-682, APR 2014. (12/05027-1, 08/56258-8)

MAXIMO, GUILHERME J.; CARARETO, NATALIA D. D.; COSTA, MARIANA C.; DOS SANTOS, ADENILSON O.; CARDOSO, LISANDRO P.; KRAEHENBAHL, MARIA A.; MEIRELLES, ANTONIO J. A.. On the solid-liquid equilibrium of binary mixtures of fatty alcohols and fatty acids. Fluid Phase Equilibria, v. 366, p. 88-98, MAR 25 2014. (09/54137-1, 12/05027-1, 08/56258-8)

BELTING, PATRICIA C.; GMEHLING, JUERGEN; BOELTS, RAINER; RAREY, JUERGEN; CERIANI, ROBERTA; CHIAVONE-FILHO, OSVALDO; MEIRELLES, ANTONIO J. A.. Measurement, correlation and prediction of isothermal vapor-liquid equilibria of different systems containing vegetable oils. Fluid Phase Equilibria, v. 395, p. 15-25, JUN 15 2015. (10/16634-0, 09/54137-1, 08/56258-8)

ROBUSTILLO, MARIA DOLORES; BARBOSA, DEISE FERNANDA; DE ALMEIDA MEIRELLES, ANTONIO JOSE; PESSOA FILHO, PEDRO DE ALCANTARA. Solid-liquid equilibrium in ternary mixtures of ethyl laurate, ethyl palmitate and ethyl myristate. Fluid Phase Equilibria, v. 361, p. 188-199, JAN 15 2014. (10/18355-1, 08/56258-8)

BELTING, PATRICIA C.; RAREY, JURGEN; GMEHLING, JURGEN; CERIANI, ROBERTA; CHIAVONE-FILHO, OSVALDO; MEIRELLES, ANTONIO J. A.. Measurements of activity coefficients at infinite dilution in vegetable oils and capric acid using the dilutor technique. Fluid Phase Equilibria, v. 361, p. 215-222, JAN 15 2014. (10/16634-0, 09/54137-1, 08/56258-8)

ROBUSTILLO, MARIA DOLORES; DE ALMEIDA MEIRELLES, ANTONIO JOSE; PESSOA FILHO, PEDRO DE ALCANTARA. Solid-liquid equilibrium of binary and ternary systems formed by ethyl laurate, ethyl palmitate and dodecylcylohexane: Experimental data and thermodynamic modeling. Fluid Phase Equilibria, v. 409, p. 157-170, FEB 15 2016. (10/18355-1, 14/17585-4, 08/56258-8)

OLIVEIRA, MARIANA B.; FOLLEGATTI-ROMERO, LUIS A.; LANZA, MARCELO; BATISTA, FABIO R. M.; BATISTA, EDUARDO A. C.; MEIRELLES, ANTONIO J. A.. Low pressure vapor-liquid equilibria modeling of biodiesel related systems with the Cubic-Plus-Association (CPA) equation of state. FUEL, v. 133, p. 224-231, OCT 1 2014. (08/56258-8)

ROBUSTILLO, MARIA DOLORES; BARBOSA, DEISE FERNANDA; DE ALMEIDA MEIRELLES, ANTONIO JOSE; PESSOA FILHO, PEDRO DE ALCANTARA. Solid-liquid equilibrium of binary and ternary mixtures containing ethyl oleate, ethyl myristate and ethyl stearate. Fluid Phase Equilibria, v. 370, p. 85-94, MAY 25 2014. (10/18355-1, 08/56258-8)

BASSO, RODRIGO CORREA; DE ALMEIDA MEIRELLES, ANTONIO JOSE; CALDAS BATISTA, EDUARDO AUGUSTO. Densities and Viscosities of Fatty Acid Ethyl Esters and Biodiesels Produced by Ethanolysis from Palm, Canola, and Soybean Oils: Experimental Data and Calculation Methodologies. Industrial & Engineering Chemistry Research, v. 52, n. 8, p. 2985-2994, FEB 27 2013. (08/56258-8)

MAXIMO, G. J.; COSTA, M. C.; MEIRELLES, A. J. A.. Solid-liquid equilibrium of triolein with fatty alcohols. Brazilian Journal of Chemical Engineering, v. 30, n. 1, p. 33-43, JAN-MAR 2013. (09/54137-1, 08/56258-8)

ROBUSTILLO, MARIA DOLORES; BARBOSA, DEISE FERNANDA; DE ALMEIDA MEIRELLES, ANTONIO JOSE; PESSOA FILHO, PEDRO DE ALCANTARA. Solid-liquid equilibrium in ternary mixtures of ethyl oleate, ethyl laurate and ethyl palmitate. Fluid Phase Equilibria, v. 339, p. 58-66, FEB 15 2013. (10/18355-1, 08/56258-8)

SILVA, SIMONE M.; SAMPAIO, KLICIA A.; CERIANI, ROBERTA; VERHE, ROLAND; STEVENS, CHRISTIAN; DE GREYT, WIM; MEIRELLES, ANTONIO J. A.. Adsorption of carotenes and phosphorus from palm oil onto acid activated bleaching earth: Equilibrium, kinetics and thermodynamics. Journal of Food Engineering, v. 118, n. 4, p. 341-349, OCT 2013. (10/16634-0, 08/56258-8)

BASSO, RODRIGO CORREA; SODRE DA SILVA, CESAR AUGUSTO; SOUSA, CAMILA DE OLIVEIRA; DE ALMEIDA MEIRELLES, ANTONIO JOSE; CALDAS BATISTA, EDUARDO AUGUSTO. LLE experimental data, thermodynamic modeling and sensitivity analysis in the ethyl biodiesel from macauba pulp oil settling step. Bioresource Technology, v. 131, p. 468-475, 2013. (08/56258-8)

BOROS‚ L.; BATISTA‚ MLS; VAZ‚ R.V.; FIGUEIREDO‚ BR; FERNANDES‚ VFS; COSTA‚ MC; KRAHENBUHL‚ MA; MEIRELLES‚ AJA; COUTINHO‚ JAP. Crystallization behavior of mixtures of fatty acid ethyl esters with ethyl stearate. ENERGY & FUELS, v. 23, n. 9, p. 4625-4629, 2009. (05/53095-2, 08/56258-8, 08/09502-0)

MAXIMO, GUILHERME J.; COSTA, MARIANA C.; MEIRELLES, ANTONIO J. A.. The Crystal-T algorithm: a new approach to calculate the SLE of lipidic mixtures presenting solid solutions. Physical Chemistry Chemical Physics, v. 16, n. 31, p. 16740-16754, AUG 21 2014. (12/05027-1, 08/56258-8)

SAWADA, MIRIAN MEGUMI; VENANCIO, LARISSA LOPES; TODA, TATIANE AKEMI; RODRIGUES, CHRISTIANNE E. C.. Effects of different alcoholic extraction conditions on soybean oil yield, fatty acid composition and protein solubility of defatted meal. Food Research International, v. 62, p. 662-670, AUG 2014. (10/03058-1, 09/17855-3, 11/09543-1, 08/56258-8, 11/14246-6)

BESSA, LARISSA C. B. A.; FERREIRA, MARCELA C.; ABREU, CHARLLES R. A.; BATISTA, EDUARDO A. C.; MEIRELLES, ANTONIO J. A.. A new UNIFAC parameterization for the prediction of liquid-liquid equilibrium of biodiesel systems. Fluid Phase Equilibria, v. 425, p. 98-107, OCT 15 2016. (09/54137-1, 08/56258-8)

T. P. V. B. DIAS; P. MIELKE NETO; M. ANSOLIN; L. A. FOLLEGATTI-ROMERO; E. A. C. BATISTA; A. J. A. MEIRELLES. LIQUID-LIQUID EQUILIBRIUM FOR TERNARY SYSTEMS CONTAINING ETHYLIC BIODIESEL + ANHYDROUS ETHANOL + REFINED VEGETABLE OIL (SUNFLOWER OIL, CANOLA OIL AND PALM OIL): EXPERIMENTAL DATA AND THERMODYNAMIC MODELING. Brazilian Journal of Chemical Engineering, v. 32, n. 3, p. 699-706, 2015-09-00. (08/56258-8, 12/09646-8)

ROBUSTILLO, MARIA DOLORES; BRANCO ALMEIDA BESSA, LARISSA CASTELLO; DE ALMEIDA MEIRELLES, ANTONIO JOSE; PESSOA FILHO, PEDRO DE ALCANTARA. Experimental data and thermodynamic modeling of solid-liquid equilibrium of binary systems containing representative compounds of biodiesel and fossil fuels: Ethyl esters and n-hexadecane. FUEL, v. 220, p. 303-317, MAY 15 2018. (10/18355-1, 14/21252-0, 08/56258-8)

QUISPE JIMENEZ, OTTO ALBERTO; LEMOS, VANESSA VILELA; CALDAS BATISTA, EDUARDO AUGUSTO; ROLEMBERG, MARLUS PINHEIRO; BASSO, RODRIGO CORREA. Hansen solubility parameters and thermodynamic modeling for LLE description during glycerol-settling in ester production from coconut oil. FUEL, v. 241, p. 725-732, APR 1 2019. (08/56258-8)

SHIOZAWA, SIMONE; BESSA, LARISSA C. B. A.; FERREIRA, MARCELA C.; MEIRELLES, ANTONIO J. A.; BATISTA, EDUARDO A. C.. Liquid-Liquid Equilibrium Data for Fatty Systems Containing Monoacylglycerols and Diacylglycerols. JOURNAL OF CHEMICAL AND ENGINEERING DATA, v. 60, n. 8, p. 2371-2379, AUG 2015. (08/56258-8)

DE MATOS, FLAVIO CARDOSO; DA COSTA, MARIANA CONCEICAO; DE ALMEIDA MEIRELLES, ANTONIO JOSE; CALDAS BATISTA, EDUARDO AUGUSTO. Binary solid-liquid equilibrium systems containing fatty acids, fatty alcohols and triolein by differential scanning calorimetry. Fluid Phase Equilibria, v. 404, p. 1-8, OCT 25 2015. (12/05027-1, 08/56258-8)

TODA, TATIANE AKEMI; SAWADA, MIRIAN MEGUMI; RODRIGUES, CHRISTIANNE E. C.. Kinetics of soybean oil extraction using ethanol as solvent: Experimental data and modeling. FOOD AND BIOPRODUCTS PROCESSING, v. 98, p. 1-10, APR 2016. (10/03058-1, 14/09446-4, 09/17855-3, 11/09543-1, 08/56258-8, 13/25142-2)

BESSA, LARISSA C. B. A.; FERREIRA, MARCELA C.; RODRIGUES, CHRISTIANNE E. C.; BATISTA, EDUARDO A. C.; MEIRELLES, ANTONIO J. A.. Simulation and process design of continuous countercurrent ethanolic extraction of rice bran oil. Journal of Food Engineering, v. 202, p. 99-113, JUN 2017. (09/54137-1, 08/56258-8, 14/21252-0, 14/09446-4)

CARARETO, NATALIA D. D.; DOS SANTOS, ADENILSON O.; ROLEMBERG, MARLUS P.; CARDOSO, LISANDRO P.; COSTA, MARIANA C.; MEIRELLES, ANTONIO J. A.. On the solid-liquid phase diagrams of binary mixtures of even saturated fatty alcohols: Systems exhibiting peritectic reaction. Thermochimica Acta, v. 589, p. 137-147, AUG 10 2014. (08/09502-0, 07/06162-1, 12/05027-1, 08/56258-8)

RODRIGUES, CHRISTIANNE E. C.; GONCALVES, CINTIA B.; MARCON, ELAINE C.; BATISTA, EDUARDO A. C.; MEIRELLES, ANTONIO J. A.. Deacidification of rice bran oil by liquid-liquid extraction using a renewable solvent. Separation and Purification Technology, v. 132, p. 84-92, AUG 20 2014. (11/02476-7, 01/13733-9, 12/23203-1, 08/56258-8, 99/12033-1)

MAXIMO, GUILHERME J.; SANTOS, RICARDO J. B. N.; BRANDAO, PAULA; ESPERANCA, JOSE M. S. S.; COSTA, MARIANA C.; MEIRELLES, ANTONIO J. A.; FREIRE, MARA G.; COUTINHO, JOAO A. P.. Generating Ionic Liquids from Ionic Solids: An Investigation of the Melting Behavior of Binary Mixtures of Ionic Liquids. Crystal Growth & Design, v. 14, n. 9, p. 4270-4277, SEP 2014. (12/05027-1, 08/56258-8)

CUEVAS, MAITE S.; CREVELIN, EDUARDO J.; DE MORAES, LUIZ A. B.; OLIVEIRA, ALESSANDRA L.; RODRIGUES, CHRISTIANNE E. C.; MEIRELLES, ANTONIO J. A.. Solubility of commercial octacosanol in organic solvents and their correlation by thermodynamic models at different temperatures. JOURNAL OF CHEMICAL THERMODYNAMICS, v. 110, p. 186-192, JUL 2017. (14/21252-0, 14/09446-4, 15/07370-3, 07/06170-4, 08/56258-8)

BELTING, PATRICIA C.; GMEHLING, JURGEN; BOLTS, RAINER; RAREY, JURGEN; CERIANI, ROBERTA; CHIAVONE-FILHO, OSVALDO; MEIRELLES, ANTONIO J. A.. Excess enthalpies for pseudobinary mixtures containing vegetable oils at the temperatures 298.15 K, 353.15 K and 383.15 K. Fluid Phase Equilibria, v. 375, p. 124-133, AUG 15 2014. (10/16634-0, 09/54137-1, 08/56258-8)

DE MATOS, FLAVIO CARDOSO; DA COSTA, MARIANA CONCEICAO; DE ALMEIDA MEIRELLES, ANTONIO JOSE; CALDAS BATISTA, EDUARDO AUGUSTO. Binary solid-liquid equilibrium systems containing fatty acids, fatty alcohols and trilaurin by differential scanning calorimetry. Fluid Phase Equilibria, v. 423, p. 74-83, SEP 15 2016. (12/05027-1, 08/56258-8)

HIRATA, GLAUCIA F.; ABREU, CHARLLES R. A.; BESSA, LARISSA C. B. A.; FERREIRA, MARCELA C.; BATISTA, EDUARDO A. C.; MEIRELLES, ANTONIO J. A.. Liquid-liquid equilibrium of fatty systems: A new approach for adjusting UNIFAC interaction parameters. Fluid Phase Equilibria, v. 360, p. 379-391, DEC 25 2013. (09/54137-1, 08/56258-8)

BESSA, LARISSA C. B. A.; FERREIRA, M. C.; BATISTA, EDUARDO A. C.; MEIRELLES, ANTONIO J. A.. Performance and cost evaluation of a new double-effect integration of multicomponent bioethanol distillation. ENERGY, v. 63, p. 1-9, DEC 15 2013. (09/54137-1, 08/56258-8)

SILVA, SIMONE M.; SAMPAIO, KLICIA A.; CERIANI, ROBERTA; VERHE, ROLAND; STEVENS, CHRISTIAN; DE GREYT, WIM; MEIRELLES, ANTONIO J. A.. Effect of type of bleaching earth on the final color of refined palm oil. LWT-FOOD SCIENCE AND TECHNOLOGY, v. 59, n. 2, 2, SI, p. 1258-1264, DEC 2014. (10/16634-0, 08/56258-8)

DIAS, T. P. V. B.; NETO, P. MIELKE; ANSOLIN, M.; FOLLEGATTI-ROMERO, L. A.; BATISTA, E. A. C.; MEIRELLES, A. J. A.. LIQUID-LIQUID EQUILIBRIUM FOR TERNARY SYSTEMS CONTAINING ETHYLIC BIODIESEL plus ANHYDROUS ETHANOL plus REFINED VEGETABLE OIL (SUNFLOWER OIL, CANOLA OIL AND PALM OIL): EXPERIMENTAL DATA AND THERMODYNAMIC MODELING. Brazilian Journal of Chemical Engineering, v. 32, n. 3, p. 699-706, JUL-SEP 2015. (12/09646-8, 08/56258-8)

FREITAS, SAMUEL V. D.; SANTOS, ANGELA; MOITA, MARIA-LUISA C. J.; FOLLEGATTI-ROMERO, LUIS A.; DIAS, TELMA P. V. B.; MEIRELLES, ANTONIO J. A.; DARIDON, JEAN-LUC; LIMA, ALVARO S.; COUTINHO, JOAO A. P.. Measurement and prediction of speeds of sound of fatty acid ethyl esters and ethylic biodiesels. FUEL, v. 108, p. 840-845, JUN 2013. (08/56258-8)

BELTING, PATRICIA CASTRO; RAREY, JUERGEN; GMEHLING, JUERGEN; CERIANI, ROBERTA; CHIAVONE-FILHO, OSVALDO; MEIRELLES, ANTONIO J. A.. Activity coefficient at infinite dilution measurements for organic solutes (polar and non-polar) in fatty compounds - Part II: C18 fatty acids. JOURNAL OF CHEMICAL THERMODYNAMICS, v. 60, p. 142-149, MAY 2013. (10/16634-0, 09/54137-1, 08/56258-8)

FERREIRA, MARCELA C.; MEIRELLES, ANTONIO J. A.; BATISTA, EDUARDO A. C.. Study of the Fusel Oil Distillation Process. Industrial & Engineering Chemistry Research, v. 52, n. 6, p. 2336-2351, FEB 13 2013. (08/56258-8)

ANSOLIN, MARINA; BASSO, RODRIGO CORREA; DE ALMEIDA MEIRELLES, ANTONIO JOSE; CALDAS BATISTA, EDUARDO AUGUSTO. Experimental data for liquid-liquid equilibrium of fatty systems with emphasis on the distribution of tocopherols and tocotrienols. Fluid Phase Equilibria, v. 338, p. 78-86, JAN 25 2013. (08/56258-8)

BOSCHETTO, DAIANE L.; DALMOLIN, IREDE; DE CESARO, ALANA M.; RIGO, ALINE A.; FERREIRA, SANDRA R. S.; MEIRELES, M. ANGELA A.; BATISTA, EDUARDO A. C.; VLADIMIR OLIVEIRA, J.. Phase behavior and process parameters effect on grape seed extract encapsulation by SEDS technique. INDUSTRIAL CROPS AND PRODUCTS, v. 50, p. 352-360, OCT 2013. (08/56258-8)

DIAS, TELMA P. V. B.; FONSECA, LUCIANA A. A. P.; RUIZ, MAIRA C.; BATISTA, FABIO R. M.; BATISTA, EDUARDO A. C.; MEIRELLES, ANTONIO J. A.. Vapor-Liquid Equilibrium of Mixtures Containing the Following Higher Alcohols: 2-Propanol, 2-Methyl-1-propanol, and 3-Methyl-1-butanol. JOURNAL OF CHEMICAL AND ENGINEERING DATA, v. 59, n. 3, p. 659-665, MAR 2014. (09/54137-1, 12/08792-0, 08/56258-8)

COSTA, MARIANA C.; ROLEMBERG, MARLUS P.; MEIRELLES, ANTONIO J. A.; COUTINHO, JOAO A. P.; KRAEHENBUEHL, M. A.. The solid-liquid phase diagrams of binary mixtures of even saturated fatty acids differing by six carbon atoms. Thermochimica Acta, v. 496, n. 1-2, p. 30-37, Dec. 2009. (08/09502-0, 05/53095-2, 08/56258-8)