Comparison of the regiospecific distribution from triacylglycerols after chemical and enzymatic interesterification of high oleic sunflower oil and fully hydrogenated high oleic sunflower oil blend by carbon-13 nuclear magnetic resonance

Autor(es)

Lopes, Thiago I. B. ^[1] ; Ribeiro, Marilene D. M. M. ^[2] ; Ming, Chiu C. ^[2] ; Grimaldi, Renato ^[2] ; Goncalves, Lireny A. G. ^[2] ; Marsaioli, Anita J. ^[1]

Afiliação do(s) autor(es)

^[1] State Univ Campinas UNICAMP, Inst Chem, BR-13083970 Campinas, SP - Brazil

^[2] State Univ Campinas UNICAMP, Fac Food Engn, BR-13083970 Campinas, SP - Brazil

• Tipo de documento: Artigo Científico
• Fonte: Food Chemistry; v. 212, p. 641-647, DEC 1 2016.
• Citações Web of Science: 5

Resumo

The nutritional and organoleptic attributes of oils can proceed via interesterification of oils blends catalyzed by enzymes or chemicals. Enzymatic interesterification processes are preferred due the regiospecific outcome. Traditionally, monitoring of distribution of fatty acids (FA) in glycerol backbone is performed by enzymatic and chromatographic methods that are time-consuming, involving a series of chemical manipulations employing large volumes of organic solvents. Alternatively, carbon-13 nuclear magnetic resonance (C-13 NMR) is a fast and reliable technique that could be applied to determine the saturated and unsaturated FA distribution of the triacylglycerols (TAGs) present in high oleic sunflower oil (SO) and fully hydrogenated high oleic sunflower oil (HSO) blends and their interesterification products. The enzymatic interesterification was conducted employing the immobilized lipase from Thermomyces lanuginosus (Lipozyme TL IM), the results show that the process was not completely regiospecific at sn-1,3 positions, due to the spontaneous acyl migration from position sn-2 to sn-1,3. (C) 2016 Elsevier Ltd. All rights reserved. (AU)

• Processo FAPESP: 12/09318-0 - Desenvolvimento e aplicação de estudos metabolômicos por rmn na investigação do perfil metabólico de pacientes obesos submetidos a cirurgia bariátrica
• Beneficiário: Thiago Inácio Barros Lopes
• Modalidade de apoio: Bolsas no Brasil - Doutorado