| Texto completo | |
| Autor(es): |
Livi, Sebastien
[1, 2, 3]
;
Lins, Luanda C.
[4]
;
Capeletti, Larissa B.
[1, 2]
;
Chardin, Charline
[5]
;
Halawani, Nour
[3]
;
Baudoux, Jerome
[5]
;
Cardoso, Mateus B.
[1, 2, 4]
Número total de Autores: 7
|
| Afiliação do(s) autor(es): | [1] CNPEM, Lab Nacl Nanotecnol LNNano, Caixa Postal 6192, BR-13083970 Campinas, SP - Brazil
[2] CNPEM, LNLS, Caixa Postal 6192, BR-13083970 Campinas, SP - Brazil
[3] Univ Lyon, CNRS, UMR 5223, Ingn Mat Polymeres, INSA Lyon, F-69621 Villeurbanne - France
[4] Univ Estadual Campinas, UNICAMP, Inst Quim, Caixa Postal 6154, BR-13083970 Campinas, SP - Brazil
[5] Univ Normandie, CNRS, ENSICAEN, Lab Chim Mol & Thioorgan, 6 Blvd Marechal Juin, F-14050 Caen - France
Número total de Afiliações: 5
|
| Tipo de documento: | Artigo Científico |
| Fonte: | EUROPEAN POLYMER JOURNAL; v. 116, p. 56-64, JUL 2019. |
| Citações Web of Science: | 1 |
| Resumo | |
The design of new highly effective polymer materials as active surfaces or coatings against microorganisms such as Escherichia coli (E. coli) is a major challenge for public health. In the present work, novel imidazolium ionic liquid monomers (ILMs) having a similar structure of conventional Bisphenol A diglycidyl ether epoxy prepolymer (DGEBA) have been designed without requiring to the use of toxic and carcinogenic compounds i.e. Bisphenol A and epichlorohydrin. Then, a facile and efficient polyaddition reaction-based polymerization via a one step process was used in order to prepare unprecedented antibacterial epoxy-amine networks. The ultimate role of the monomers architecture on the epoxy conversion as well as on the reactivity of the epoxy-functionalized imidazolium ionic liquid monomers with an aliphatic amine (D-230) was investigated while the average molecular weight between crosslinks (Mc) and the relaxation temperature of the resulting networks were determined. Thus, new epoxy thermosets with an excellent thermal stability, high hydrophobic behavior and good storage modulus at room temperature were produced. Finally, antimicrobial tests against E. coli were performed for the first time on these new cross-linked epoxy networks leading to a very strong inhibition of E. coli biofilm formation (- 95%). (AU) | |
| Processo FAPESP: | 17/11060-5 - Desenvolvimento de hidrogéis supramoleculares injetáveis baseados em peptídos RGD modificados |
| Beneficiário: | Luanda Chaves Vieira Lins |
| Modalidade de apoio: | Bolsas no Brasil - Pós-Doutorado |
| Processo FAPESP: | 17/26471-0 - Concepção de novas nanopartículas de sílica com base em líquidos iônicos para aplicações biomédicas |
| Beneficiário: | Mateus Borba Cardoso |
| Modalidade de apoio: | Auxílio à Pesquisa - Pesquisador Visitante - Internacional |
| Processo FAPESP: | 15/25406-5 - Organizando a matéria: colóides formados por associação de surfactantes, polímeros e nanopartículas |
| Beneficiário: | Watson Loh |
| Modalidade de apoio: | Auxílio à Pesquisa - Temático |
| Processo FAPESP: | 17/01167-7 - Nanopartículas de sílica funcionalizadas com oligômeros de carboidratos e sua interação com a membrana bacteriana |
| Beneficiário: | Larissa Brentano Capeletti |
| Modalidade de apoio: | Bolsas no Brasil - Pós-Doutorado |