The origin of the unusual DSC peaks of supercooled barium disilicate liquid

Autor(es)

Moulton, Benjamin J. A. ^{[1, 2]} ; Rodrigues, Alisson M. ^[1] ; Sampaio, David V. ^{[1, 2]} ; Silva, Lais D. ^[1] ; Cunha, Thiago R. ^[2] ; Zanotto, Edgar D. ^[1] ; Pizani, Paulo S. ^{[1, 2]}

Afiliação do(s) autor(es)

^[1] Univ Fed Sao Carlos, Dept Mat Engn, CERTEV Ctr Res Technol & Educ Vitreous Mat, BR-13565905 Sao Carlos, SP - Brazil

^[2] Univ Fed Sao Carlos, Dept Fis, Km 235, BR-13565905 Sao Carlos, SP - Brazil

• Tipo de documento: Artigo Científico
• Fonte: CrystEngComm; v. 21, n. 17, p. 2768-2778, MAY 7 2019.
• Citações Web of Science: 0

Resumo

It is known that barium disilicate (BS2) glass exhibits two prominent exothermic peaks between the glass transition and melting temperatures in calorimetric experiments, however, their cause is not known. In this work, glass-ceramic samples were produced inside a differential scanning calorimeter (DSC) and then investigated ex situ with X-ray diffraction (XRD) and Raman spectroscopy. We found that the first exothermic peak results from multiphase crystallization although a signature of residual glass is still observed. H-BaSi2O5, and Ba3Si5O13 were directly identified after the first exothermic peak, however, both L-BaSi2O5 and an unknown phase(s) are also formed. Rietveld analysis indicates <1% Ba(3)Si(5)0(13) in the sample heat treated at 853 degrees C (the first exothermic peak maximum). Amorphous halos are observed in the XRD patterns of samples heated to temperatures until the second exothermic peak. Raman spectra suggest that the crystalline phases are somewhat distorted or contain defects. The second exothermic peak is actually a composite peak composed of two contributions. We interpret these shoulders as separate processes including crystallization of non-stoichiometric phases, crystallization of the residual glass, and the phase transition of monoclinic H-BaSi2O5 to orthorhombic L-BaSi2O5. After the second exothermic peak, the XRD and Raman spectra show that the samples have become L-BaSi2O5. These results clarify the relationships between thermal history and crystalline phase formation, which may be used to produce glass-ceramics with desirable properties. (AU)

• Processo FAPESP: 16/15962-0 - Correlação entre estrutura e propriedades dinâmicas e ópticas de materiais da série (Ax, A'1-x)O + SiO2 (A, A' = Pb, Ni, Co, Fe, Cr): estudo por espalhamento Raman e simulações por dinâmica molecular
• Beneficiário: David Vieira Sampaio
• Modalidade de apoio: Bolsas no Brasil - Pós-Doutorado
• Processo FAPESP: 16/18567-5 - Ordenamento estrutural pré-nucleação em vidros que nucleiam homogeneamente: BaO-2SiO2 e CaO-SiO2
• Beneficiário: Benjamin John Albert Moulton
• Modalidade de apoio: Bolsas no Brasil - Pós-Doutorado