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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

The origin of the unusual DSC peaks of supercooled barium disilicate liquid

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Author(s):
Moulton, Benjamin J. A. [1, 2] ; Rodrigues, Alisson M. [1] ; Sampaio, David V. [1, 2] ; Silva, Lais D. [1] ; Cunha, Thiago R. [2] ; Zanotto, Edgar D. [1] ; Pizani, Paulo S. [1, 2]
Total Authors: 7
Affiliation:
[1] Univ Fed Sao Carlos, Dept Mat Engn, CERTEV Ctr Res Technol & Educ Vitreous Mat, BR-13565905 Sao Carlos, SP - Brazil
[2] Univ Fed Sao Carlos, Dept Fis, Km 235, BR-13565905 Sao Carlos, SP - Brazil
Total Affiliations: 2
Document type: Journal article
Source: CrystEngComm; v. 21, n. 17, p. 2768-2778, MAY 7 2019.
Web of Science Citations: 0
Abstract

It is known that barium disilicate (BS2) glass exhibits two prominent exothermic peaks between the glass transition and melting temperatures in calorimetric experiments, however, their cause is not known. In this work, glass-ceramic samples were produced inside a differential scanning calorimeter (DSC) and then investigated ex situ with X-ray diffraction (XRD) and Raman spectroscopy. We found that the first exothermic peak results from multiphase crystallization although a signature of residual glass is still observed. H-BaSi2O5, and Ba3Si5O13 were directly identified after the first exothermic peak, however, both L-BaSi2O5 and an unknown phase(s) are also formed. Rietveld analysis indicates <1% Ba(3)Si(5)0(13) in the sample heat treated at 853 degrees C (the first exothermic peak maximum). Amorphous halos are observed in the XRD patterns of samples heated to temperatures until the second exothermic peak. Raman spectra suggest that the crystalline phases are somewhat distorted or contain defects. The second exothermic peak is actually a composite peak composed of two contributions. We interpret these shoulders as separate processes including crystallization of non-stoichiometric phases, crystallization of the residual glass, and the phase transition of monoclinic H-BaSi2O5 to orthorhombic L-BaSi2O5. After the second exothermic peak, the XRD and Raman spectra show that the samples have become L-BaSi2O5. These results clarify the relationships between thermal history and crystalline phase formation, which may be used to produce glass-ceramics with desirable properties. (AU)

FAPESP's process: 16/15962-0 - Correlation between materials structure and dynamic and optical properties of (Ax, A'1-x)O + SiO2 (A, A' = Pb, Ni, Co, Fe, Cr) series: Raman scattering and molecular dynamics simulations
Grantee:David Vieira Sampaio
Support Opportunities: Scholarships in Brazil - Post-Doctoral
FAPESP's process: 16/18567-5 - Nuclei entrapment: the pre-nucleation structural ordering of homogeneous nucleating BaO-2SiO2 and CaO-SiO2 glasses
Grantee:Benjamin John Albert Moulton
Support Opportunities: Scholarships in Brazil - Post-Doctoral