Effective recovery of ytterbium through biosorption using crosslinked sericin-alginate beads: A complete continuous packed-bed column study

Autor(es)

da Costa, Talles Barcelos ^[1] ; Carlos da Silva, Meuris Gurgel ^[1] ; Adeodato Vieira, Melissa Gurgel ^[1]

Afiliação do(s) autor(es)

^[1] Univ Estadual Campinas, Sch Chem Engn, Albert Einstein Ave, BR-13083852 Campinas - Brazil

• Tipo de documento: Artigo Científico
• Fonte: JOURNAL OF HAZARDOUS MATERIALS; v. 421, JAN 5 2022.
• Citações Web of Science: 1

Resumo

The recovery of rare-earth from secondary sources is essential for cleaner production. The development of natural biocomposites is promising for this purpose. Sericin is a waste protein from silk manufacturing. The highly polar groups on the surface of sericin facilitate blending and crosslinking with other polymers to produce biocomposites with improved properties. In this work, we investigate ytterbium recovery onto a natural biocomposite based on sericin/alginate/poly(vinyl alcohol) (SAPVA) in packed-bed column, aiming to establish a profitable application for sericin. Effects of flow rate and ytterbium inlet concentration showed that the highest exhaustion biosorption capacity (128.39 mg/g) and lowest mass transfer zone (4.13 cm) were reached under the operating conditions of 0.03 L/h and 87.95 mg/L. Four reusability cycles were performed under the optimum operating conditions using 0.3 mol/L HNO3. Ytterbium recovery was highly successful; desorption efficiency was higher than 97% and a final ytterbium-rich concentrate (3870 mg/L) was 44 times higher than input concentration. Regenerated beads characterization showed that the cation exchange mechanism plays a major function in continuous biosorption of ytterbium. SAPVA beads also showed higher biosorption/desorption performance for ytterbium than other competing ions. These results suggest the application of SAPVA may be an alternative for large-scale ytterbium recovery. (AU)

• Processo FAPESP: 17/18236-1 - Recuperação de íons metálicos nobres e íons terras-raras presentes em soluções aquosas por bioadsorção em partículas de blenda de sericina e alginato
• Beneficiário: Melissa Gurgel Adeodato Vieira
• Modalidade de apoio: Auxílio à Pesquisa - Regular
• Processo FAPESP: 19/11353-8 - Centro Brasileiro de Pesquisa em Água (BWRC)
• Beneficiário: Lauro Tatsuo Kubota
• Modalidade de apoio: Auxílio à Pesquisa - Programa Centros de Pesquisa em Engenharia