Photochemistry with visible light using donor-acceptor diazocompounds

• Grant number: 19/01235-8
• Support Opportunities: Regular Research Grants
• Start date: May 01, 2020
• End date: June 30, 2022
• Field of knowledge: Physical Sciences and Mathematics - Chemistry - Organic Chemistry
• Principal Investigator: Igor Dias Jurberg
• Grantee: Igor Dias Jurberg
• Host Institution: Instituto de Química (IQ). Universidade Estadual de Campinas (UNICAMP). Campinas , SP, Brazil

Abstract

This project aims at the development of new applications involving the generation of free carbenes from the blue light irradiation of aryldiazoacetates. (AU)

Scientific publications

(9)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

MUNARETTO, LAIELI S.; DOS SANTOS, CAIO Y.; GALLO, RAFAEL D. C.; OKADA JR, CELSO Y.; DEFLON, VICTOR M.; JURBERG, IGOR D.. Visible-Light-Mediated Strategies to Assemble Alkyl 2-Carboxylate-2,3,3-Trisubstituted beta-Lactams and 5-Alkoxy-2,2,4-Trisubstituted Furan-3(2H)-ones Using Aryldiazoacetates and Aryldiazoketones. ORGANIC LETTERS, v. 23, n. 23, p. 9292-9296, DEC 3 2021. (19/01235-8, 20/00144-6)

GALLO, RAFAEL D. C.; DUARTE, MARCELO; DA SILVA, AMANDA F.; OKADA, JR., CELSO Y.; DEFLON, VICTOR M.; JURBERG, IGOR D.. Selective C-C Bond Cleavage Strategy Promoted by Visible Ligh. ORGANIC LETTERS, v. 23, n. 22, p. 8916-8920, NOV 19 2021. (20/00144-6, 19/01235-8)

STIVANIN, MATEUS L.; GALLO, RAFAEL D. C.; SPADETO, JOAO PAULO M.; CORMANICH, RODRIGO A.; JURBERG, IGOR D.. visible light-mediated three-component strategy based on the ring-opening of cyclic ethers with aryldiazoacetates and nucleophile. ORGANIC CHEMISTRY FRONTIERS, v. 9, n. 5, p. 1321-1326, MAR 1 2022. (20/00144-6, 20/06536-3, 18/03910-1, 19/01235-8)

STIVANIN, MATEUS L.; DUARTE, MARCELO; LEAO, LUIZ PAULO M. O.; SAITO, FELIPE A.; JURBERG, IGOR D.. isible-Light-Mediated Strategies for the Preparation of Oxime Ethers Derived from O-H Insertions of Oximes into Aryldiazoacetate. Journal of Organic Chemistry, v. 86, n. 23, p. 17528-17532, DEC 3 2021. (20/02107-0, 19/01235-8)

JURBERG, IGOR D.; NOME, RENE A.; CRESPI, STEFANO; ATVARS, TERESA D. Z.; KOENIG, BURKHARD. Visible Light-Enhanced C-H Amination of Cyclic Ethers with Iminoiodinanes. ADVANCED SYNTHESIS & CATALYSIS, v. N/A, p. 9-pg., 2022-11-23. (20/10541-2, 09/14153-8, 19/01235-8)

BERLINCK, ROBERTO G. S.; BERNARDI, I, DARLON; FILL, TAICIA; FERNANDES, ALESSANDRA A. G.; JURBERG, IGOR D.. The chemistry and biology of guanidine secondary metabolites. NATURAL PRODUCT REPORTS, v. 38, n. 3, p. 586-667, MAR 1 2021. (13/50228-8, 19/06359-7, 19/01235-8, 16/21341-9, 17/22164-6)

QUEVEDO-ACOSTA, YOVANNY; JURBERG, IGOR D.; GAMBA-SANCHEZ, DIEGO. Cyclization Strategies Using Imide Derivatives for the Synthesis of Polycyclic Nitrogen-Containing Compounds. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, v. 2022, n. 36, p. 22-pg., 2022-07-05. (19/01235-8)

YANG, ZHEN; STIVANIN, MATEUS L.; JURBERG, IGOR D.; KOENIGS, RENE M.. Visible light-promoted reactions with diazo compounds: a mild and practical strategy towards free carbene intermediates. CHEMICAL SOCIETY REVIEWS, v. 49, n. 19, p. 15-pg., 2020-10-07. (19/01235-8)

MUNARETTO, LAIELI S.; GALLO, RAFAEL D. C.; LEAO, LUIZ PAULO M. O.; JURBERG, IGOR D.. H-F bond insertions into alpha-diazo carbonyl compounds. ORGANIC & BIOMOLECULAR CHEMISTRY, v. 20, n. 31, p. 5-pg., 2022-03-24. (20/00144-6, 19/01235-8)