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Exploratory analysis of functional lipidomics in the COVID-19 pathophysiology: molecular targets, metabolism and biochemical reprogramming due to hypoxia

Abstract

Lipids represent the majority of biomolecules comprised in metabolomics. In this sense, a functional lipidomic configures an integrative strategy for the identification of bioactive lipids, membrane lipids composition, interactions of lipids with signaling proteins and metabolism enzymes. Consequently, lipids can influence pathological processes, such as inflammation and signaling of the tissue microenvironment. COVID-19 disease, caused by the SARS-CoV-2 coronavirus, can cause mild to critical illness. The critical cases present an exacerbated inflammatory response, and the lung may be the organ most affected. Metabolic diseases are mandatory as risk factors for COVID-19, but the mechanisms related to metabolism, especially those involving lipids, remain unclear. On the other hand, SARS-CoV-2 possesses a virus capsid surrounded by a lipid bilayer and the role of lipids in a viral infection comprises the fusion of the virus membrane to the host cell until the viral replication process. In this project, we propose a multidisciplinary approach to study the functional lipidomics applied in the pathophysiological processes of COVID-19, and we will use hypoxia as a model to evaluate biochemical reprogramming in this disease. Thus, we intend to: i) describe the plasma lipid composition of patients with COVID-19 in the broad severity illness; ii) characterize cell activation/signaling and metabolism pathways in blood leukocytes; iii) obtaining the monocytes subpopulations, determining their lipid composition and gene expression by Single-cell Lipidomics; iv) using the monocyte's lipidomics data for chemical imaging (MALDI) approach in bronchoalveolar lavage matrix or lung biopsy slides; v) determine the correlation of lipid metabolism and its bioactive metabolites in the modulation of SARS-CoV-2-induced inflammation and infectivity in monocytes in vitro, and vi) consider hypoxia as a modulator of lipid metabolism (in vivo and in vitro) and determine its effects on the disease pathology. Therefore, this study will clarify the involvement of lipid species in COVID-19 development and may suggest new molecular therapeutic targets. (AU)

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Scientific publications (9)
(The scientific publications listed on this page originate from the Web of Science or SciELO databases. Their authors have cited FAPESP grant or fellowship project numbers awarded to Principal Investigators or Fellowship Recipients, whether or not they are among the authors. This information is collected automatically and retrieved directly from those bibliometric databases.)
FUZO, CARLOS A.; FRAGA-SILVA, THAIS F. C.; MARUYAMA, SANDRA R.; BASTOS, VICTOR A. F.; ROGERIO, LUANA A.; TAKAMIYA, NAYORE T.; DA SILVA-NETO, PEDRO V.; PIMENTEL, VINICIUS E.; TORO, DIANA M.; PEREZ, MALENA M.; et al. The turning point of COVID-19 severity is associated with a unique circulating neutrophil gene signature. IMMUNOLOGY, v. 169, n. 3, p. 21-pg., . (15/00658-1, 21/04590-3, 20/08534-8, 20/05207-6, 19/09881-6, 14/07125-6, 20/05270-0, 17/16328-6)
DA SILVA-NETO, PEDRO, V; DO VALLE, VALERIA B.; FUZO, CARLOS A.; FERNANDES, TALITA M.; TORO, DIANA M.; FRAGA-SILVA, THAIS F. C.; BASILE, PATRICIA A.; DE CARVALHO, JONATAN C. S.; PIMENTEL, VINICIUS E.; PEREZ, MALENA M.; et al. Matrix Metalloproteinases on Severe COVID-19 Lung Disease Pathogenesis: Cooperative Actions of MMP-8/MMP-2 Axis on Immune Response through HLA-G Shedding and Oxidative Stress. BIOMOLECULES, v. 12, n. 5, p. 20-pg., . (14/07125-6, 20/08534-8, 20/05270-0, 14/23946-0, 21/04590-3, 20/05207-6)
DA SILVA-NETO, PEDRO V.; DE CARVALHO, JONATAN C. S.; TORO, DIANA M.; OLIVEIRA, BIANCA T. M.; COMINAL, JUCARA G.; CASTRO, RICARDO C.; ALMEIDA, MARIA A.; PRADO, CIBELE M.; ARRUDA, EURICO; FRANTZ, FABIANI G.; et al. TREM-1-Linked Inflammatory Cargo in SARS-CoV-2-Stimulated Macrophage Extracellular Vesicles Drives Cellular Senescence and Impairs Antibacterial Defense. Viruses-Basel, v. 17, n. 5, p. 20-pg., . (23/07776-6, 24/03414-5, 21/04590-3, 22/07287-2)
DUARTE-SILVA, MURILLO; OLIVEIRA, CAMILLA N. S.; FUZO, CARLOS; SILVA-NETO, PEDRO V.; TORO, DIANA M.; PIMENTEL, VINICIUS E.; PEREZ, MALENA M.; FRAGA-SILVA, THAIS F. C.; CARVALHO, JONATAN C. S.; NETO, FIRMINO M. S.; et al. Divergent androgenic modulation of SARS-CoV-2 infection cooperates with dysregulated immune response to dictate worse COVID-19 outcomes in men. BRAIN BEHAVIOR AND IMMUNITY, v. 114, p. 12-pg., . (15/00658-1, 20/05270-0, 21/04590-3, 20/05207-6)
TORO, DIANA MOTA V.; DA SILVA-NETO, PEDRO V.; DE CARVALHO, JONATAN C. S. A.; FUZO, CARLOS A. M.; PEREZ, MALENA M.; PIMENTEL, VINICIUS E.; FRAGA-SILVA, THAIS F. C.; OLIVEIRA, CAMILLA N. S. R.; CARUSO, GLAUCIA R.; VILELA, ADRIANA F. L.; et al. Plasma Sphingomyelin Disturbances: Unveiling Its Dual Role as a Crucial Immunopathological Factor and a Severity Prognostic Biomarker in COVID-19. CELLS, v. 12, n. 15, p. 23-pg., . (20/08534-8, 15/00658-1, 20/05270-0, 20/05207-6, 21/04590-3, 14/07125-6)
DE CARVALHO, JONATAN C. S.; DA SILVA-NETO, PEDRO V.; TORO, DIANA M.; FUZO, CARLOS A.; NARDINI, VIVIANI; PIMENTEL, VINICIUS E.; PEREZ, MALENA M.; FRAGA-SILVA, THAIS F. C.; OLIVEIRA, CAMILLA N. S.; DEGIOVANI, AUGUSTO M.; et al. The Interplay among Glucocorticoid Therapy, Platelet-Activating Factor and Endocannabinoid Release Influences the Inflammatory Response to COVID-19. Viruses-Basel, v. 15, n. 2, p. 22-pg., . (15/00658-1, 21/04590-3, 20/08534-8, 20/05207-6, 14/07125-6, 22/07287-2, 20/05270-0)
FELIPPE, THIAGO V. D.; TORO, DIANA M.; DE CARVALHO, JONATAN C. S.; NOBRE-AZEVEDO, PEDRO; RODRIGUES, LUIZ F. M.; OLIVEIRA, BIANCA T. M.; DA SILVA-NETO, PEDRO V.; VILELA, ADRIANA F. L.; ALMEIDA, FAUSTO; FACCIOLI, LUCIA H.; et al. High-resolution targeted mass spectrometry for comprehensive quantification of sphingolipids: clinical applications and characterization of extracellular vesicles. Analytical Biochemistry, v. 698, p. 12-pg., . (24/03414-5, 21/04590-3, 23/07776-6, 14/07125-6, 20/05207-6, 15/00658-1)
CORDEIRO, JESSICA F. C.; FERNANDES, TALITA M.; TORO, DIANA M.; DA SILVA-NETO, PEDRO, V; PIMENTEL, VINICIUS E.; PEREZ, MALENA M.; DE CARVALHO, JONATAN C. S.; FRAGA-SILVA, THAIS F. C.; OLIVEIRA, CAMILLA N. S.; ARGOLO, JAMILLE G. M.; et al. The Severity of COVID-19 Affects the Plasma Soluble Levels of the Immune Checkpoint HLA-G Molecule. INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, v. 23, n. 17, p. 16-pg., . (20/05207-6, 20/08534-8, 20/05270-0, 21/04590-3)
VILELA, ADRIANA F. L.; PATRICIO, MIGUEL R.; NOBRE-AZEVEDO, PEDRO; DE CARVALHO, JONATAN C. S.; DEFELIPPO-FELIPPE, THIAGO, V; PONTES, NATHAN N. H.; RODRIGUES, DANIEL L.; OLIVEIRA, BIANCA T. M.; DA SILVA-NETO, PEDRO V.; NARDINI, VIVIANI; et al. Enhanced lipidomics workflows for plasma and extracellular vesicles through advanced liquid chromatography-tandem mass spectrometry integrated. Talanta, v. 291, p. 13-pg., . (22/07287-2, 24/03414-5, 21/04590-3)