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Impact of sampling and analytical uncertainties on conformity assessment of pharmaceutical products

Grant number:22/08406-5
Support Opportunities:Regular Research Grants
Start date: November 01, 2022
End date: October 31, 2024
Field of knowledge:Health Sciences - Pharmacy - Medicines Analysis and Control
Principal Investigator:Felipe Rebello Lourenço
Grantee:Felipe Rebello Lourenço
Host Institution: Faculdade de Ciências Farmacêuticas (FCF). Universidade de São Paulo (USP). São Paulo , SP, Brazil
City of the host institution:São Paulo

Abstract

Analytical results are often used in scientific research, industrial and clinical applications to support decision making. Despite all efforts to ensure the reliability of analytical results (including method validation, internal quality control, use of certified reference materials, proficiency tests, and ISO 17025 accreditation), there will always be an uncertainty associated with the measured value. The measurement uncertainty expresses the quality of the analytical result and allows the comparability between analytical results or between the measured value and the specification limit(s). This work will study the impact of sampling and analytical uncertainties on conformity assessment of pharmaceutical products. The measurement uncertainty arising from sampling will be assess using simulations methods (such as Monte Carlo and Bootstrapping methods) and/or by experimental determination of sample heterogeneity. Analytical measurement uncertainty will be assess using top-down and/or bottom-up approaches. The impact of sampling and analytical measurement uncertainty on conformity assessment will be studied be determining the risk of false conformity decisions and/or applying the guard band concepts. Where relevant, strategies will be proposed to reduce uncertainty, whether associated with sampling or the analytical stage, in order to ensure appropriate final uncertainty values for use. The project also aims to establish the procedures for estimating the risk of false decisions in situations where asymmetric distribution is expected. (AU)

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Scientific publications (17)
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
SILVA, MATHEUS BERGAMINI; LOURENCO, FELIPE REBELLO. Measurement uncertainty for (788) Particulate matter in injections - uncertainties arising from sampling and analytical steps. Microchemical Journal, v. 210, p. 10-pg., . (22/08406-5)
BERTANHA, MARIA LUIZA DE GODOY; LOURENCO, FELIPE REBELLO. Total combined risk of false conformity decisions in pharmaceutical equivalence of acetaminophen oral solution. Microchemical Journal, v. 201, p. 6-pg., . (22/08406-5)
CAFFARO, ARTHUR M.; LOURENCO, FELIPE R.. Total combined global risk assessment applied to pharmaceutical equivalence - A case study of ofloxacin medicines. CHEMOMETRICS AND INTELLIGENT LABORATORY SYSTEMS, v. 241, p. 9-pg., . (22/08406-5)
SANO, ADRIANO Y.; LOURENCO, FELIPE R.. Measurement uncertainty arising from sampling and analytical steps of dissolution test of prednisone tablets. Journal of Pharmaceutical and Biomedical Analysis, v. 234, p. 7-pg., . (22/08406-5)
PASSARIN, PAULA BEATRIZ SILVA; LOURENCO, FELIPE REBELLO. Enhancing analytical development in the pharmaceutical industry: A DoE-QSRR model for virtual Method Operable Design Region assessment. Journal of Pharmaceutical and Biomedical Analysis, v. 239, p. 12-pg., . (22/08406-5)
BERTANHA, MARIA LUIZA DE GODOY; LOURENCO, FELIPE REBELLO. Impact of metrological correlation on the total combined risk in pharmaceutical equivalence evaluations. CHEMOMETRICS AND INTELLIGENT LABORATORY SYSTEMS, v. 255, p. 8-pg., . (22/08406-5)
CINTIA MARGUEIRO DA SILVA; FELIPE REBELLO LOURENÇO. Multivariate guard-bands and total risk assessment on multiparameter evaluations with correlated and uncorrelated measured values. Brazilian Journal of Pharmaceutical Sciences, v. 60, . (22/08406-5)
PASSARIN, PAULA BEATRIZ SILVA; OKAMOTO, ROGERIO TAKAO; DORR, FABIANE; YONAMINE, MAURICIO; LOURENCO, FELIPE REBELLO. AQbD approach for the development of an analytical procedure for the separation of cephalosporin drugs and their degradation products. CHEMOMETRICS AND INTELLIGENT LABORATORY SYSTEMS, v. 261, p. 15-pg., . (22/08406-5)
LOURENCO, FELIPE REBELLO; BETTENCOURT DA SILVA, RICARDO J. N.. Simplified and Detailed Evaluations of the Uncertainty of the Measurement of Microbiological Contamination of Pharmaceutical Products. JOURNAL OF AOAC INTERNATIONAL, v. 107, n. 5, p. 12-pg., . (22/08406-5)
MARTINS, MAISA TORRES; LOURENCO, FELIPE REBELLO. Measurement uncertainty for <711> Dissolution tests using Monte Carlo methods - Uncertainties arising from sampling and analytical steps. Analytica Chimica Acta, v. 1330, p. 10-pg., . (22/08406-5)
COUTO, ALDO RENATO; SILVA PASSARIN, PAULA BEATRIZ; LOURENCO, FELIPE R.. Risk of false conformity decisions in LAL gel-clot test due to false-negative results. CHEMOMETRICS AND INTELLIGENT LABORATORY SYSTEMS, v. 234, p. 6-pg., . (22/08406-5)
GUSTAVO KENJI TOKO PURCINO DO AMARAL; FELIPE REBELLO LOURENÇO. Risk of false conformity decisions due to measurement uncertainty of Active Pharmaceutical Ingredient: A multiparametric evaluation. Brazilian Journal of Pharmaceutical Sciences, v. 60, . (22/08406-5)
CRIVILARI, VICTORIA APARECIDA VIT; DOS SANTOS, JEAN BISPO; LOURENCO, FELIPE REBELLO. Impact of sample heterogeneity on the evaluation of uncertainty from sampling and analytical steps in pharmaceutical analysis. Journal of Pharmaceutical and Biomedical Analysis, v. 255, p. 7-pg., . (22/08406-5)
SANO, ADRIANO Y.; LOURENCO, FELIPE R.. Measurement uncertainty arising from sampling and analytical steps of dissolution test of glyburide tablets. Microchemical Journal, v. 196, p. 6-pg., . (22/08406-5)
MARTINS, MAISA TORRES; LOURENCO, FELIPE REBELLO. Measurement uncertainty for < 905 > Uniformity of Dosage Units tests using Monte Carlo and bootstrapping methods - Uncertainties arising from sampling and analytical steps. Journal of Pharmaceutical and Biomedical Analysis, v. 238, p. 8-pg., . (22/08406-5)
KRAPIENIS, MICHELLY GONCALVES; LOURENCO, FELIPE REBELLO. Agar diffusion microbiological assay measurement using a smartphone device and its measurement uncertainty using the bootstrapping method. Microchemical Journal, v. 200, p. 5-pg., . (22/08406-5)