Synthesis of new catalysts based on gold nanoparticles supported on carbon nanotubes. Application in selective hydrogenation reactions

• Grant number: 07/05820-5
• Support Opportunities: Regular Research Grants
• Start date: February 01, 2008
• End date: April 30, 2010
• Field of knowledge: Physical Sciences and Mathematics - Chemistry - Organic Chemistry
• Principal Investigator: Regina Buffon
• Grantee: Regina Buffon
• Host Institution: Instituto de Química (IQ). Universidade Estadual de Campinas (UNICAMP). Campinas , SP, Brazil
• City of the host institution: Campinas

Abstract

This work deals with the preparation and characterization of gold nanoparticles supported on carbon nanotubes. The resulting systems will be tested in the selective hydrogenation of alpha,beta-unsaturated aldehydes and ketones, nitrocompounds, imines and in the selective hydrogenation of benzene to cyclohexene (in batch). The materials will be characterized by several spectroscopic techniques, by electron transmission and scanning microscopy, by nitrogen adsorption/desorption and by ICP-EAS (to determine de gold loading). (AU)