Porous materials and composites chemically modified with zirconium (IV) and phosphoric acid: Preparation and electroanalytical applications.

• Grant number: 13/08495-9
• Support Opportunities: Scholarships in Brazil - Doctorate
• Start date: October 01, 2013
• End date: July 31, 2016
• Field of knowledge: Engineering - Materials and Metallurgical Engineering - Nonmetallic Materials
• Principal Investigator: Devaney Ribeiro Do Carmo
• Grantee: Tayla Fernanda Serantoni da Silveira
• Host Institution: Faculdade de Engenharia (FEIS). Universidade Estadual Paulista (UNESP). Campus de Ilha Solteira. Ilha Solteira , SP, Brazil

Abstract

In this project describes spectroscopic and electroanalytical properties of inorganofunctionalized spongolite (or micellar template silica) with zirconium (IV) and also of composite formed between the Zr (IV) and phosphoric acid following a new synthetic route . In a first step, it is intended to prepare and characterize by spectroscopic techniques (Nuclear Magnetic Resonance in solid state (NMR), Infrared Spectroscopy (FTIR), Thermogravimetric Analysis and Differential Thermal Analysis (TGA-DTA), Ultraviolet Visible Spectroscopy (UV-Visible), X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), Energy Dispersive X-ray (EDX)), the inorganofunctionalized matrix with Zr (IV) and a composite formed between Zr (IV) and phosphoric acid. The voltammetric behavior of these supracited materials, after surface interaction with electron mediators, such as anionic (potassium hexacyanoferrate and / or sodium nitroprusside) and cationic (phenothiazines, ferrocene and others) species, will be tested. Therefore these studies aim the mounting of analytical systems for the determination of drugs and other species of biological interest, using cyclic voltammetry, differential pulse voltammetry, square wave voltammetry and chronoamperometry. Additionally it is intended to test the catalytic properties these materials in the selective conversion of glycerol into acrolein (an important intermediate for the production of acrylic acid).

Scientific publications

(4)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

SILVESTRINI, DANIELA RODRIGUES; SERANTONI DA SILVEIRA, TAYLA FERNANDA; BICALHO, URQUISA DE OLIVEIRA; DO CARMO, DEVANEY RIBEIRO. Voltammetric Behavior of a Chemically Modified Silsesquioxane with 4-Amino-5-Phenyl-4h-[1,2,4]-Triazole-3-Thiol and its Application for Detection of L-Dopamine. International Journal of Electrochemical Science, v. 10, n. 4, p. 2839-2858, APR 2015. (13/08495-9, 12/05438-1, 12/11306-0)

DO CARMO, DEVANEY RIBEIRO; SERANTONI DA SILVEIRA, TAYLA FERNANDA. A New Composite Based on Electroactive Zirconium Phosphate: Morfology, Structure and Their Behavior as a Voltammetric Sensor in the Ascorbic Acid Detection. Journal of Inorganic and Organometallic Polymers and Materials, v. 29, n. 4, p. 1205-1218, JUL 2019. (12/05438-1, 13/08495-9)

SERANTONI DA SILVEIRA, TAYLA FERNANDA; FERNANDES, DANIELA SILVESTRINI; BARBOSA, PRISCILA FERNANDA P.; DO CARMO, DEVANEY RIBEIRO. Preparation and use of a Grafted Silica with Imidazole Groups for Cadmium Sorption and Subsequent Voltammetric Detection of Ascorbic Acid. SILICON, v. 10, n. 2, p. 635-643, MAR 2018. (12/05438-1, 12/11306-0, 13/08495-9)

DO CARMO, DEVANEY R.; SILVESTRINI, DANIELA R.; DA SILVEIRA, TAYLA F. S.; CUMBA, LOANDA R.; DIAS FILHO, NEWTON L.; SOARES, LAYCIANE A.. Silsesquioxane organofunctionalized with 4-amino-3-hydrazino-5-mercapto-1,2,4-triazole: Preparation and subsequent reaction with silver and potassium hexacyanoferrate(III) for detection of L-cysteine. Materials Science & Engineering C-Materials for Biological Applications, v. 57, p. 24-30, DEC 1 2015. (13/08495-9, 12/05438-1, 12/11306-0)

Academic Publications

(References retrieved automatically from State of São Paulo Research Institutions)

SILVEIRA, Tayla Fernanda Serantoni da. Porous materials and composites chemically modified with zirconium (IV) and phosphoric acid: preparation and electroanalytical applications. 2016. Doctoral Thesis - Universidade Estadual Paulista (Unesp). Faculdade de Engenharia. Ilha Solteira Ilha Solteira.