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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Tailoring the properties of acetate-based ionic liquids using the tricyanomethanide anion

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Lepre, L. F. ; Szala-Bilnik, J. ; Padua, A. A. H. ; Traikia, M. ; Ando, R. A. ; Gomes, M. F. Costa
Total Authors: 6
Document type: Journal article
Source: Physical Chemistry Chemical Physics; v. 18, n. 33, p. 23285-23295, SEP 7 2016.
Web of Science Citations: 9

The equilibrium and transport properties of mixtures of two ionic liquids - {[}C(4)C(1)Im]{[}OAc] and {[}C(4)C(1)Im]{[}C(CN)(3)] - were determined and interpreted at the molecular level using vibration spectroscopy, NMR and molecular dynamics simulation. The non-ideality of the mixtures {[}C(4)C(1)Im]{[}OAc]((1-x)){[}C(CN)(3)](x) was characterized by V-E = +0.28 cm(3) mol(-1) (293 K, x = 0.65) and H-E = -2.2 kJ mol(-1) for x = 0.5. These values could be explained by a rearrangement of the hydrogen-bond network of the mixture that favours the interaction of the acetate anion with the imidazolium cation at position C2. The dynamic properties of the mixture are also dramatically influenced by the composition with a decrease of the viscosity and an increase of self-diffusion coefficients of the ions when the amount of tricyanomethanide anion increases in the mixture. (AU)

FAPESP's process: 15/07145-0 - Ionic liquids for carbon dioxide capture
Grantee:Luiz Fernando Lepre
Support type: Scholarships abroad - Research Internship - Doctorate
FAPESP's process: 13/23234-7 - Ionic Liquids for CO2 Capture: Physical vs. Chemical Absorption.
Grantee:Luiz Fernando Lepre
Support type: Scholarships in Brazil - Doctorate