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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Synthesis of ZnWO4 by the polymerizable complex method: Evidence of amorphous phase coexistence during the phase formation process

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Author(s):
Gondim, Magda S. S. [1] ; Silva, Eliezer C. [2] ; dos Santos, Ananias L. [2] ; de Assis, Marcelo [3] ; Mercury, Jose M. R. [1] ; Leite, Edson R. [3, 4] ; Nogueira, Icamira C. [5]
Total Authors: 7
Affiliation:
[1] Fed Inst Maranhao, PPGEM, BR-65030005 Sao Luis, MA - Brazil
[2] Univ Fed Amazonas, PPGCEM, BR-69077000 Manaus, AM - Brazil
[3] Univ Fed Sao Carlos, Chem Dept, BR-13565905 Sao Carlos, SP - Brazil
[4] CNPEM, Brazilian Nanotechnol Natl Lab LNNano, BR-13083100 Campinas, SP - Brazil
[5] Univ Fed Amazonas, Phys Dept, BR-69077000 Manaus, AM - Brazil
Total Affiliations: 5
Document type: Journal article
Source: CERAMICS INTERNATIONAL; v. 47, n. 13, p. 19073-19078, JUL 1 2021.
Web of Science Citations: 0
Abstract

In this paper, we report on a new path of ZnWO4 phase formation, synthesized by the polymerizable complex (PC) method. At 550 degrees C, we obtained a single phase of the ZnWO4 complex oxide. To explain the phase transformation processes, we propose a mechanism based on the coexistence of more than one amorphous phase after the pre-pyrolysis process. These amorphous metastable phases indicate a different phase formation path, which has not yet been described in the literature for multi-component oxides processed by the PC method. The formation path proposed here shows the relevance of the metastable phases in the reaction processes of complex oxides. (AU)

FAPESP's process: 13/07296-2 - CDMF - Center for the Development of Functional Materials
Grantee:Elson Longo da Silva
Support Opportunities: Research Grants - Research, Innovation and Dissemination Centers - RIDC