Fluorine and sodium depletion followed by refractive index modification imprinted on fluorophosphate glass surface by thermal poling

Author(s)

Galleani, Gustavo ; Abou Khalil, Alain ; Canioni, Lionel ; Dussauze, Marc ; Fargin, Evelyne ; Cardinal, Thierry ; de Camargo, Andrea S. S.

• Document type: Journal article
• Source: Journal of Non-Crystalline Solids; v. 601, p. 7-pg., 2023-02-01.

Abstract

Thermal poling using microstructured electrodes on oxyfluoride glasses have been investigated and the impact on optical properties was evaluated. A micrometer refractive index modification based on the sodium and fluorine migration has been evidenced, through the creation of a layer with different chemical composition as compared to the original glass. Topological and optical properties modifications after poling treatment are discussed. For the first time, we described the migration of negative fluorine ion in the direction of the cathode from the glass network. Na and F migration led to a layer richer in oxides with a strong contrast of + 0.06 of the refractive index in the imprinted structures. (AU)

• FAPESP's process: 13/07793-6 - CEPIV - Center for Teaching, Research and Innovation in Glass
• Grantee: Edgar Dutra Zanotto
• Support Opportunities: Research Grants - Research, Innovation and Dissemination Centers - RIDC
• FAPESP's process: 19/12442-4 - Thermal poling of oxyfluoride glasses: generation of second order non-linear properties (SONL) and surface modification by microimprinting
• Grantee: Gustavo Galleani
• Support Opportunities: Scholarships abroad - Research Internship - Post-doctor