Doped Carbon Quantum Dots/PVA Nanocomposite as a Platform to Sense Nitrite Ions in Meat

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Carneiro, Samuel Veloso ; Oliveira, Jose Joelson Pires ; Rodrigues, Vivian Stephanie Ferreira ; Fechine, Lillian Maria Uchoa Dutra ; Antunes, Renato Altobelli ; Neto, Manoel Lourenco Alves ; Moura, Thiago Alves de ; Cesar, Carlos Lenz ; de Carvalho, Hernandes Faustino ; Paschoal, Alexandre Rocha ; Freire, Rafael Melo ; Fechine, Pierre Basilio Almeida

• Document type: Journal article
• Source: ACS APPLIED MATERIALS & INTERFACES; v. N/A, p. 15-pg., 2022-09-14.

Abstract

A sensor device based on doped-carbon quantum dots is proposed herein for detection of nitrite in meat products by fluorescence quenching. For the sensing platform, carbon quantum dots doped with boron and functionalized with nitrogen (B,N-Cdot) were synthesized with an excellent 44.3% quantum yield via a one-step hydrothermal route using citric acid, boric acid, and branched polyethylenimine as carbon, boron, and nitrogen sources, respectively. After investigation of their chemical structure and fluorescent properties, the B,N-Cdot at aqueous suspensions showed high selectivity for NO2- in a linear range from 20 to 50 mmol L-1 under optimum conditions at pH 7.4 and a 340 nm excitation. Furthermore, the prepared B,N-Cdots successfully detected NO2- in a real meat sample with recovery of 91.4-104% within the analyzed range. In this manner, a B,N-Cdot/PVA nanocomposite film with blue emission under excitation at 360 nm was prepared, and a first assay detection of NO2- in meat products was tested using a smartphone application. The potential application of the newly developed sensing device containing a highly fluorescent probe should aid in the development of a rapid and inexpensive strategy for NO2- detection. (AU)

• FAPESP's process: 14/50938-8 - INCT 2014: in Photonics Applied to Cell Biology
• Grantee: Hernandes Faustino de Carvalho
• Support Opportunities: Research Projects - Thematic Grants